35 Ill. Adm. Code 218.110
Vapor Pressure of Organic Material or Solvent
Section 218
Section 218.110 Vapor
Pressure of Organic Material or Solvent
a) If the organic material or solvent consists of only a single
compound, the vapor pressure shall be determined by ASTM Method D2879-86
(incorporated by reference in Section 218.112 of this Part) or the vapor
pressure may be obtained from a publication such as: Boublik, T., V. Fried and
E. Hala, "The Vapor Pressure of Pure Substances," Elsevier Scientific
Publishing Co., New York (1973); Perry's Chemical Engineer's Handbook,
McGraw-Hill Book Company (1984); CRC Handbook of Chemistry and Physics, Chemical
Rubber Publishing Company (1986-87); and Lange's Handbook of Chemistry, John A.
Dean, editor, McGraw-Hill Book Company (1985).
b) If the organic material or solvent is in a mixture made up of
both organic material compounds and compounds which are not organic material,
the vapor pressure shall be determined by the following equation:
where:
P
om
=
Total vapor pressure of the
portion of the mixture which is composed of organic material;
n
=
Number of organic material components
in the mixture;
i
=
Subscript denoting an
individual component;
P
i
=
Vapor pressure of an organic
material component determined in accordance with subsection (a) of this
Section;
X
i
=
Mole fraction of the organic
material component of the total organic mixture.
c) If the organic material or solvent is in a mixture made up of
only organic material compounds, the vapor pressure shall be determined by ASTM
Method D2879-86 (incorporated by reference in Section 218.112 of this Part) or
by the above equation.