35 Ill. Adm. Code 742.APPENDIX C
C Tier 2 Illustrations and Tables
Section 742.APPENDIX CÂ Â Tier
2 Illustrations and Tables
Section 742.TABLE EÂ Â Default
Physical and Chemical Parameters
e
CAS
No.
Chemical
Solubility
in Water (S) (mg/L)
Diffusivity
in Air (D
i
) (cm
2
/s)
Diffusivity
in Water (D
w
) (cm
2
/s)
Dimensionless
Henry's Law Constant (H') (25°C)
Dimensionless
Henry's Law Constant (H') (13°C)
For
the indoor inhalation exposure route
Organic
Carbon Partition Coefficient (K
oc
) (L/kg)
First
Order Degradation Constant (
l
)(d
-1
)
Vapor
Pressure (mm/Hg)
Neutral
Organics
83-32-9
Acenaphthene
3.60E+00
4.76E-02
7.69E-06
6.60E-03
-------
b
6.30E+03
3.40E-03
2.50E-03
67-64-1
Acetone
1.00E+06
1.24E-01
1.14E-05
1.60E-03
9.73E-04
7.80E-01
4.95E-02
2.30E+02
15972-60-8
Alachlor
2.40E+02
2.13E-02
5.28E-06
3.40E-06
-------
b
3.20E+03
No
Data
2.20E-05
116-06-3
Aldicarb
6.03E+03
3.18E-02
7.24E-06
5.90E-08
-------
b
1.29E+01
1.09E-03
3.47E-05
309-00-2
Aldrin
1.70E-02
1.96E-02
4.86E-06
7.00E-03
-------
b
2.50E+05
5.90E-04
6.00E-06
120-12-7
Anthracene
4.30E-02
3.85E-02
7.74E-06
2.70E-03
-------
b
2.50E+04
7.50E-04
2.70E-06
1912-24-9
Atrazine
7.00E+01
2.59E-02
6.67E-06
9.68E-08
-------
b
3.63E+02
No
Data
2.70E-07
71-43-2
Benzene
1.80E+03
8.80E-02
1.02E-05
2.30E-01
1.34E-01
5.00E+01
9.00E-04
9.50E+01
56-55-3
Benzo(a)anthracene
9.40E-03
5.10E-02
9.00E-06
1.39E-04
-------
b
4.00E+05
5.10E-04
1.10E-07
205-99-2
Benzo(b)fluoranthene
1.50E-03
2.23E-02
5.56E-06
4.55E-03
-------
b
1.05E+06
5.70E-04
5.00E-07
207-08-9
Benzo(k)fluoranthene
8.00E-04
2.23E-02
5.56E-06
3.40E-05
-------
b
1.00E+06
1.60E-04
2.00E-09
65-85-0
Benzoic
Acid
3.40E+03
7.02E-02
7.97E-06
1.56E-06
-------
b
1.21E+00
d
No
Data
7.00E-04
50-32-8
Benzo(a)pyrene
1.60E-03
4.30E-02
9.49E-06
4.50E-05
-------
b
7.90E+05
6.50E-04
5.50E-09
111-44-4
Bis(2-chloroethyl)
ether
1.72E+04
4.13E-02
7.53E-06
7.40E-04
2.94E-04
1.26E+01
1.90E-03
1.55E+00
117-81-7
Bis(2-ethylhexyl)phthalate
3.40E-01
3.51E-02
3.66E-06
4.10E-06
-------
b
1.00E+05
1.80E-03
6.80E-08
75-27-4
Bromodichloromethane
6.70E+03
5.61E-02
1.06E-05
6.60E-02
3.71E-02
5.00E+01
No
Data
5.00E+01
75-25-2
Bromoform
3.10E+03
1.49E-02
1.03E-05
2.19E-02
1.06E-02
9.12E+01
1.90E-03
5.51E+00
71-36-3
Butanol
7.40E+04
8.00E-02
9.30E-06
3.61E-04
1.55E-04
6.00E+00
1.28E-02
7.00E+00
78-93-3
2-Butanone
(MEK)
2.20E+05
8.08E-02
9.8E-06
2.30E-03
1.32E-03
2.00E+00
4.95E-02
9.50E+01
85-68-7
Butyl
Benzyl Phthalate
2.70E+00
1.99E-02
4.89E-06
5.30E-05
-------
b
6.30E+04
3.85E-03
8.30E-06
86-74-8
Carbazole
1.20E+00
4.17E-02
7.45E-06
3.60E-06
-------
b
4.00E+03
No
Data
7.00E-04
1563-66-2
Carbofuran
3.20E+02
2.37E-02
5.95E-06
1.27E-07
-------
b
1.91E+02
No
Data
4.85E-06
75-15-0
Carbon
Disulfide
1.20E+03
1.04E-01
1.00E-05
1.23E+00
8.06E-01
6.30E+01
No
Data
3.60E+02
56-23-5
Carbon
Tetrachloride
7.90E+02
7.80E-02
8.80E-06
1.23E+00
7.48E-01
2.00E+02
1.90E-03
1.20E+02
57-74-9
Chlordane
5.60E-02
1.79E-02
4.37E-06
2.00E-03
-------
b
2.50E+05
2.50E-04
9.80E-06
106-47-8
p-Chloroaniline
5.30E+03
6.99E-02
1.01E-05
4.76E-05
-------
b
6.31E+01
No
Data
1.23E-02
108-90-7
Chlorobenzene
4.70E+02
7.30E-02
8.70E-06
1.50E-01
7.93E-02
2.00E+02
2.30E-03
1.20E+01
124-48-1
Chlorodibromomethane
2.60E+03
3.66E-02
1.05E-05
3.20E-02
2.07E-02
6.92E+01
3.85E-03
4.90E+00
67-66-3
Chloroform
7.90E+03
1.04E-01
1.00E-05
1.50E-01
9.18E-02
5.00E+01
3.90E-04
2.00E+02
95-57-8
2-Chlorophenol
2.20E+04
6.61E-02
9.46E-06
1.60E-02
7.28E-03
5.93E+01
d
No
Data
2.34E+00
218-01-9
Chrysene
6.30E-03
2.44E-02
6.21E-06
3.90E-03
-------
b
4.00E+05
3.50E-04
6.20E-09
94-75-7
2,4-D
6.77E+02
5.88E-02
6.49E-06
4.18E-07
-------
b
5.75E+02
3.85E-03
6.00E-07
72-54-8
4,4'-DDD
9.00E-02
2.27E-02
5.79E-06
1.60E-04
-------
b
7.90E+05
6.20E-05
6.70E-07
72-55-9
4,4'-DDE
1.20E-01
2.38E-02
5.87E-06
8.60E-04
-------
b
4.00E+05
6.20E-05
6.00E-06
50-29-3
4,4'-DDT
2.50E-02
1.99E-02
4.95E-06
3.30E-04
-------
b
2.00E+06
6.20E-05
1.60E-07
75-99-0
Dalapon
9.00E+05
6.08E-02
9.45E-06
2.64E-06
NA
4.80E+00
5.78E-03
1.90E-01
53-70-3
Dibenzo(a,h)anthracene
2.50E-03
2.11E-02
5.24E-06
6.10E-07
-------
b
2.50E+06
3.70E-04
1.00E-10
96-12-8
1,2-Dibromo-3-chloropropane
1.20E+03
2.68E-02
7.02E-06
6.20E-03
c
NA
7.90E+01
1.93E-03
5.80E-01
106-93-4
1,2-Dibromoethane
4.00E+03
4.37E-02
8.44E-06
3.00E-02
1.54E-02
5.00E+01
5.78E-03
1.30E+01
84-74-2
Di-n-butyl
Phthalate
1.10E+01
4.38E-02
7.86E-06
7.40E-05
-------
a
4.00E+04
3.01E-02
7.30E-05
1918-00-9
Dicamba
4.50E+03
2.37E-02
5.95E-06
2.18E-09
-------
a
2.95E+00
No
Data
3.38E-05
95-50-1
1,2-Dichlorobenzene
1.56E+02
6.90E-02
7.90E-06
7.79E-02
3.56E-02
5.75E+02
1.90E-03
1.36E+00
106-46-7
1,4-Dichlorobenzene
7.90E+01
6.90E-02
7.90E-06
9.80E-02
4.69E-02
7.90E+02
1.90E-03
1.00E+00
91-94-1
3,3-Dichlorobenzidine
3.10E+00
2.59E-02
6.74E-06
1.60E-07
-------
a
2.82E+03
1.90E-03
3.71E-08
75-71-8
Dichlorodifluoromethane
2.80E+02
7.60E-02
1.08E-05
1.41E+01
8.14E+00
6.17E+01
1.92E-03
4.85E+03
75-34-3
1,1-Dichloroethane
5.10E+03
7.42E-02
1.05E-05
2.30E-01
1.42E-01
3.20E+01
1.90E-03
2.30E+02
107-06-2
1,2-Dichloroethane
8.50E+03
1.04E-02
9.90E-06
4.00E-02
2.29E-02
2.00E+01
1.90E-03
7.90E+01
75-35-4
1,1-Dichloroethylene
2.30E+03
9.00E-02
1.04E-05
1.10E+00
7.10E-01
5.00E+01
5.30E-03
6.00E+02
156-59-2
cis
-1,2-Dichloroethylene
3.50E+03
8.86E-02
1.13E-05
1.70E-01
1.00E-01
4.00E+01
2.40E-04
2.00E+02
156-60-5
trans
-1,2-Dichloroethylene
6.30E+03
7.03E-02
1.19E-05
3.90E-01
2.43E-01
5.00E+01
2.40E-04
3.30E+02
120-83-2
2,4-Dichlorophenol
4.50E+03
4.89E-02
8.77E-06
1.30E-04
-------
a
7.32E+02
d
2.70E-04
6.70E-02
78-87-5
1,2-Dichloropropane
2.80E+03
7.82E-02
8.73E-06
1.10E-01
6.52E-02
5.00E+01
2.70E-04
5.20E+01
542-75-6
1,3-Dichloropropylene
(
cis
+
trans
)
2.80E+03
6.26E-02
1.00E-05
7.40E-01
3.98E-01
2.00E+01
6.10E-02
3.40E+01
60-57-1
Dieldrin
2.00E-01
1.92E-02
4.74E-06
6.2E-04
-------
a
2.50E+04
3.20E-04
5.9E-06
84-66-2
Diethyl
Phthalate
1.10E+03
2.49E-02
6.35E-06
1.80E-05
-------
a
3.20E+02
6.19E-03
1.60E-03
105-67-9
2,4-Dimethylphenol
7.90E+03
6.43E-02
8.69E-06
8.20E-05
-------
a
2.00E+02
4.95E-02
9.80E-02
75-71-8
1,3-Dinitrobenzene
8.60E+02
4.55E-02
8.46E-06
2.30E-07
-------
a
3.20E+01
1.92E-03
9.00E-04
51-28-5
2,4-Dinitrophenol
2.79E+03
2.73E-02
9.06E-06
1.82E-05
-------
a
3.24E+01
1.32E-03
5.10E-03
121-14-2
2,4-Dinitrotoluene
2.70E+02
2.03E-01
7.06E-06
3.80E-06
-------
a
8.90E+01
1.92E-03
1.47E-04
606-20-2
2,6-Dinitrotoluene
1.82E+02
3.70E-02
7.76E-06
3.06E-05
-------
a
4.90E+01
1.92E-03
5.67E-04
88-85-7
Dinoseb
5.20E+01
2.45E-02
6.25E-06
1.87E-05
-------
a
9.17E+01
d
2.82E-03
7.50E-05
117-84-0
Di-n-octyl
Phthalate
2.00E-02
1.73E-02
4.17E-06
2.74E-03
-------
a
1.30E+05
1.90E-03
2.60E-06
123-91-1
p-Dioxane
1.00E+06
2.29E-01
1.02E-05
1.97E-04
1.07E-04
7.20E-01
1.92E-03
3.81E+01
115-29-7
Endosulfan
5.10E-01
1.85E-02
4.55E-06
4.51E-04
-------
a
5.00E+03
7.63E-02
1.00E-05
145-73-3
Endothall
2.10E+04
2.91E-02
8.07E-06
1.58E-14
-------
a
7.59E+01
No
Data
1.57E-10
72-20-8
Endrin
2.50E-01
1.92E-02
4.74E-6
3.08E-04
-------
a
3.20E+04
3.20E-04
3.00E-06
100-41-4
Ethylbenzene
1.70E+02
7.50E-02
7.80E-06
3.24E-01
1.64E-01
3.20E+02
3.00E-03
9.60E+00
206-44-0
Fluoranthene
2.06E-01
2.51E-02
6.35E-06
6.60E-04
-------
a
7.40E+04
1.90E-04
1.23E-08
86-73-7
Fluorene
2.00E+00
4.40E-02
7.88E-06
2.62E-03
-------
a
1.30E+04
6.91E-04
6.30E-04
76-44-8
Heptachlor
1.80E-01
2.23E-02
5.69E-06
6.07E-02
1.73E-02
3.00E+03
1.30E-01
4.00E-04
1024-57-3
Heptachlor
epoxide
2.00E-01
2.19E-02
5.57E-06
3.90E-04
-------
a
2.00E+05
6.30E-04
1.90E-05
118-74-1
Hexachlorobenzene
6.20E-03
5.42E-02
5.91E-06
5.33E-02
1.35E-02
2.00E+04
1.70E-04
1.80E-05
319-84-6
Alpha-HCH
(alpha-BHC)
2.00E+00
2.04E-02
5.04E-06
4.51E-04
-------
a
5.00E+03
2.50E-03
4.50E-05
58-89-9
Gamma-HCH
(Lindane)
7.30E+00
2.75E-02
7.34E-06
5.74E-04
-------
a
3.00E+03
2.90E-03
4.10E-04
2691-41-0
High
Melting Explosive, Octogen (HMX)
5.00E+00
2.69E-02
7.15E-06
8.67E-10
3.55E-08
1.40E+00
No
Data
3.30E-14
77-47-4
Hexachlorocyclo-
pentadiene
1.80E+00
2.79E-02
7.21E-06
1.11E+00
4.22E-01
1.20E+04
1.20E-02
5.96E-02
67-72-1
Hexachloroethane
5.00E+01
2.50E-03
6.80E-06
1.59E-01
7.26E-02
1.50E+03
1.92E-03
2.10E-01
193-39-5
Indeno(1,2,3-c,d)pyrene
2.20E-05
2.25E-02
5.66E-06
6.56E-05
-------
a
3.10E+06
4.70E-04
1.00E-10
78-59-1
Isophorone
1.20E+04
6.23E-02
6.76E-06
2.72E-04
1.12E-04
2.50E+01
1.24E-02
4.38E-01
98-82-8
Isopropylbenzene
(Cumene)
6.10E+01
6.50E-02
7.10E-06
4.92E+01
2.10E+01
1.02E+03
4.33E-02
4.50E+00
93-65-2
Mecoprop
(MCPP)
8.95E+02
2.40E-02
6.05E-06
7.70E-09
-------
a
1.84E+01
d
3.85E-03
2.44E-05
7439-97-6
Mercury
6.00E-02
7.14E-02
3.01E-05
4.51E-01
1.59E-01
8.70E+03
No
Data
2.00E-03
72-43-5
Methoxychlor
4.50E-02
1.84E-02
4.46E-06
6.56E-04
-------
a
5.00E+04
1.90E-03
6.00E-07
74-83-9
Methyl
Bromide
1.50E+04
7.28E-02
1.21E-05
2.56E-01
1.79E-01
1.00E+01
1.82E-02
1.62E+03
1634-04-4
Methyl
tertiary-butyl ether
5.10E+04
8.59E-02
1.10E-05
2.42E-02
1.50E-02
1.00E+01
No
Data
2.50E+02
75-09-2
Methylene
Chloride
1.30E+04
1.01E-01
1.17E-05
9.02E-02
5.70E-02
1.30E+01
1.20E-02
4.30E+02
93-65-2
2-Methylnaphthalene
2.50E+01
5.22E-02
7.75E-06
2.10E-02
6.95E-03
1.60E+03
No
Data
6.80E-02
95-48-7
2-Methylphenol
(o-cresol)
2.60E+04
7.40E-02
8.30E-06
4.92E-05
2.00E-05
4.20E+01
4.95E-02
2.99E-01
91-20-3
Naphthalene
3.10E+01
5.90E-02
7.50E-06
1.97E-02
8.29E-03
5.00E+02
2.70E-03
8.50E-02
98-95-3
Nitrobenzene
2.09E+03
7.60E-02
8.60E-06
9.84E-04
3.99E-04
4.00E+01
1.76E-03
2.40E-01
86-30-6
N-Nitrosodiphenylamine
3.50E+01
2.83E-02
7.19E-06
2.10E-04
-------
a
1.00E+03
1.00E-02
6.70E-04
621-64-7
N-Nitrosodi-n-propylamine
9.89E+03
5.87E-02
8.17E-06
9.20E-05
5.48E-05
1.45E+01
1.90E-03
1.30E-01
87-86-5
Pentachlorophenol
2.00E+03
5.60E-02
6.10E-06
9.84E-07
-------
a
2.77E+03
d
4.50E-04
3.20E-05
108-95-2
Phenol
8.30E+04
8.20E-02
9.10E-06
1.64E-05
6.67E-06
2.00E+01
9.90E-02
2.80E-01
1918-02-1
Picloram
4.30E+02
2.26E-02
5.64E-06
2.19E-12
-------
a
2.00E+00
No
Data
7.21E-11
1336-36-3
Polychlorinated
biphenyls (PCBs)
-------
a
-------
a
-------
a
-------
a
-------
a
-------
a
-------
a
-------
a
129-00-0
Pyrene
1.40E+00
2.77E-02
7.24E-06
4.51E-04
-------
a
6.31E+04
1.80E-04
4.60E-06
121-82-4
Royal
Demolition Explosive, Cyclonite (RDX)
5.97E+01
3.11E-02
8.49E-06
2.01E-11
-------
a
7.20E+00
No Data
4.10E-09
122-34-9
Simazine
6.20E+00
2.48E-02
6.28E-06
3.80E-08
-------
a
1.32E+02
No
Data
2.21E-08
100-42-5
Styrene
3.10E+02
7.10E-02
8.00E-06
1.11E-01
5.48E-03
3.16E+02
3.30E-03
6.10E+00
93-72-1
2,4,5-TP
(Silvex)
7.10E+01
2.30E-02
5.83E-06
3.71E-07
-------
a
5.50E+03
No
Data
9.97E-06
127-18-4
Tetrachloroethylene
2.00E+02
7.20E-02
8.20E-06
7.38E-01
4.00E-01
6.31E+02
9.60E-04
1.90E+01
108-88-3
Toluene
5.30E+02
8.70E-02
8.60E-06
2.71E-01
1.49E-01
1.58E+02
1.10E-02
2.80E+01
8001-35-2
Toxaphene
7.40E-01
2.16E-02
5.51E-06
2.46E-04
-------
a
5.01E+04
No
Data
9.80E-07
120-82-1
1,2,4-Trichlorobenzene
3.50E+01
3.00E-02
8.23E-06
5.74E-02
2.38E-02
1.58E+03
1.90E-03
4.30E-01
71-55-6
1,1,1-Trichloroethane
1.30E+03
7.80E-02
8.80E-06
6.97E-01
4.21E-01
1.26E+02
1.30E-03
1.20E+02
79-00-5
1,1,2-Trichloroethane
4.40E+03
7.80E-02
8.80E-06
3.73E-02
1.98E-02
5.01E+01
9.50E-04
2.30E+01
79-01-6
Trichloroethylene
1.50E+03
7.90E-02
9.10E-06
4.10E-01
2.41E-01
1.00E+02
4.20E-04
7.30E+01
75-69-4
Trichlorofluoromethane
1.10E+03
8.70E-02
9.70E-06
3.98E+00
2.69E+00
1.30E+02
9.63E-04
8.00E+02
95-95-4
2,4,5-Trichlorophenol
1.20E+03
2.91E-02
7.03E-06
1.78E-04
-------
a
2.68E+03
d
3.80E-04
2.40E-02
88-06-2
2,4,6-Trichlorophenol
8.00E+02
2.61E-02
6.36E-06
3.53E-04
-------
a
8.78E+02
d
3.80E-04
2.00E-02
108-05-4
Vinyl
Acetate
2.00E+04
8.50E-02
9.20E-06
2.09E-02
1.18E-02
4.57E+00
No
Data
9.00E+01
99-35-4
1,3,5-Trinitrobenzene
2.80E+02
2.41E-02
6.08E-06
3.30E-10
-------
a
1.60E+01
No
Data
6.40E-06
118-96-7
2,4,6-Trinitrotoluene
(TNT)
1.24E+02
2.94E-02
7.90E-06
4.87E-09
-------
a
3.72E+01
1.92E-03
2.02E-06
57-01-4
Vinyl
Chloride
8.80E+03
1.06E-01
1.23E-06
1.11E+00
8.14E-01
1.58E+01
2.40E-04
3.00E+03
108-38-3
m-Xylene
1.60E+02
7.00E-02
7.80E-06
2.99E-01
1.52E-01
3.98E+02
1.90E-03
8.50E+00
95-47-6
o-Xylene
1.80E+02
8.70E-02
1.00E-05
2.13E-01
1.07E-01
3.16E+02
1.90E-03
6.60E+00
106-42-3
p-Xylene
1.60E+02
7.69E-02
8.44E-06
3.16E-01
1.59E-01
3.16E+02
1.90E-03
8.90E+00
1330-20-7
Xylenes
(total)
1.10E+02
7.35E-02
9.23E-06
2.71E-01
NA
3.98E+02
1.90E-03
8.00E+00
Chemical Abstracts Service (CAS) registry number. This
number in the format xxx-xx-x, is unique for each chemical and allows efficient
searching on computerized data bases.
a
Soil
remediation objectives are determined pursuant to 40 CFR 761, as incorporated
by reference at Section 742.210(b) (the USEPA "PCB Spill Cleanup Policy"),
for most sites; persons remediating sites should consult with BOL if
calculation of Tier 2 or 3 remediation objectives is desired. PCBs are a
mixture of different congeners. The appropriate values to use for the
physical/chemical parameters depend on congeners present at the site.
b
Dimensionless
Henry's Law Constant at 13°C is not calculated because the chemical is not
volatile and does not require evaluation under the indoor inhalation exposure
route.
c
Dimensionless Henry's Law Constant = 20°C
d
These
chemicals are ionizing and its K
oc
value will change with pH. The K
oc
values listed in this table is the effective K
oc
at pH of 6.8. If
the site-specific pH is values other than 6.8, the K
oc
value listed
Appendix C, Table I should be used.
e
The
values in this table were taken from the following sources (in order of
preference):Â SCDMS online database
(http://www.epa.gov/superfund/sites/npl/hrsres/tools/scdm.htm); CHEMFATE online
database (http://www.srcinc.com/what-we-do/databaseforms.aspx?id=381); PhysProp
online database (http://www.srcinc.com/what-we-do/databaseforms.aspx?id-386);
Water (http://www.epa.gov/ttn/chief/software/water/) for diffusivity values;
and Handbook of Environmental Degradation Rates by P.H. Howard (1991) for first
order degradation constant values.