R 336.1122 Definitions; V.

Rule 122. As used in these rules: (a) "Vacuum-metalizing coatings" means topcoats and basecoats that are used in the vacuum-metalizing process. (b) "Vacuum-producing system" means any device that creates a pressure below atmospheric, such as a pump or steam ejector with condenser, including hot wells and accumulators. (c) "Vapor collection system," as it pertains to R 336.1627, means all piping, seals, hoses, connections, pressure-vacuum vents, and equipment between and including the delivery vessel and a stationary vessel, vapor processing unit, or vapor holder. (d) [Reserved] (e) "Visible emission" means any emissions that are visually detectable without the aid of instruments. (f) "Volatile organic compound" means any compound of carbon or mixture of compounds of carbon that participates in photochemical reactions, excluding the following materials, all of which have been determined by the United States Environmental Protection Agency to have negligible photochemical reactivity: (i) Carbon monoxide (CAS No. 630-08-0). (ii) Carbon dioxide (CAS No. 124-38-9). (iii) Carbonic acid (CAS No. 463-79-6). (iv) Metallic carbides or carbonates (CAS No. not applicable). (v) Boron carbide (CAS No. 12069-32-8 or 60063-34-5). (vi) Silicon carbide (CAS No. 409-21-2 or 12327-32-1). (vii) Ammonium carbonate (CAS No. 10361-29-2 or 506-87-6). (viii) Ammonium bicarbonate (CAS No. 1066-33-7). (ix) Methane (CAS No. 74-82-8). (x) Ethane (CAS No. 74-84-0). (xi) The methyl chloroform (CAS No. 71-55-6) portion of commercial grades of methyl chloroform, if all of the following provisions are complied with: (A) The commercial grade of methyl chloroform is used only in a surface coating or coating line that is subject to the requirements part 6 or 7 of these rules. (B) The commercial grade of methyl chloroform contains no stabilizers other than those listed in table 11. (C) Compliance with the applicable limits specified in parts 6 or 7 of these rules is otherwise not technically or economically reasonable. (D) All measures to reduce the levels of all organic solvents, including the commercial grade of methyl chloroform, from the surface coating or coating line to the lowest reasonable level, are implemented. (E) The emissions of the commercial grade of methyl chloroform do not result in a maximum ambient air concentration exceeding any of the allowable ambient air concentrations listed in table 11. (F) The use of the commercial grade of methyl chloroform is specifically identified and allowed by a permit to install, permit to operate, or order of the department. (G) Table 11 reads as follows: TABLE 11. Commercial Grade of Methyl Chloroform -- Allowable Ambient Air Concentrations Compound Ppm1 Time2 Methyl chloroform 3.5 1 hour Tertiary butyl alcohol3 1.0 1 hour Secondary butyl alcohol3 1.0 1 hour Methylal3 10.0 1 hour 1,2-butylene oxide3 0.028 and 1 hour 0.00041 annual 1 Parts per million, by volume 2 Averaging time period 3 This compound is a stabilizer (xii) The methyl chloroform (CAS No. 71-55-6) portion of commercial grades of methyl chloroform that contain another stabilizer not listed in table 11 of this rule, if all of the following provisions are complied with: (A) The commercial grade of methyl chloroform is used only in a surface coating or coating line that is subject to the requirements of parts 6 or 7 of these rules. (B) Compliance with the applicable limits specified in parts 6 or 7 of these rules is otherwise not technically or economically reasonable. (C) All measures to reduce the levels of all organic solvents, including the commercial grade of methyl chloroform, from the surface coating or coating line to the lowest reasonable level are implemented. (D) The emissions of any compound in the commercial grade of methyl chloroform that is listed in table 11 of this rule do not result in a maximum ambient air concentration exceeding any of the allowable ambient air concentrations listed in table 11. (E) The emission of all compounds in the commercial grade of methyl chloroform that are not listed in table 11 is demonstrated to comply with R 336.1901. (F) The use of the commercial grade of methyl chloroform is specifically identified and allowed by a permit to install, permit to operate, or order of the department. (xiii) Acetone (CAS No. 67-64-1). (xiv) Cyclic, branched, or linear completely methylated siloxanes (CAS Nos. include 107-45-0, 107-51-7, 141-62-8, 141-63-9, 107-63-9, 63148-62-9, 541-05-9, 556-67-2, 541- 02-6, 540-97-6, 69430-24-6, 17928-28-8, 3555-47-3). (xv) Parachlorobenzotrifluoride (CAS No. 98-56-6). (xvi) Perchloroethylene (CAS No. 127-18-4). (xvii) Trichlorofluoromethane (CFC-11) (CAS No. 75-69-4). (xviii) Dichlorodifluoromethane (CFC-12) (CAS No. 75-71-8). (xix) 1,1,2-trichloro-1,2,2-trifluoroethane (CFC-113) (CAS No. 76-13-1). (xx) 1,2-dichloro 1,1,2,2-tetrafluoroethane (CFC-114) (CAS No. 76-14-2). (xxi) Chloropentafluoroethane (CFC-115) (CAS No. 76-15-3). (xxii) 1,1-dichloro 1-fluoroethane (HCFC-141b) (CAS No. 1717-00-6). (xxiii) 1,chloro 1,1-difluoroethane (HCFC-142b) (CAS No. 75-68-3). (xxiv) Chlorodifluoromethane (HCFC-22) (CAS No. 75-45-6). (xxv) 1,1,1-trifluoro 2,2-dichloroethane (HCFC-123) (CAS No. 306-83-2). (xxvi) 2-chloro-1,1,1,2-tetrafluoroethane (HCFC-124) (CAS No. 2837-89-0). (xxvii) Trifluoromethane (HFC-23) (CAS No. 75-46-7). (xxviii) Pentafluoroethane (HFC-125) (CAS No. 354-33-6). (xxix) 1,1,2,2-tetrafluoroethane (HFC-134) (CAS No. 359-35-3). (xxx) 1,1,1,2-tetrafluoroethane (HFC-134a) (CAS No. 811-97-2). (xxxi) 1,1,1-trifluoroethane (HFC-143a) (CAS No. 420-46-2). (xxxii) 1,1-difluoroethane (HFC-152a) (CAS No. 75-37-6). (xxxiii) 3,3-dichloro-1, 1,1,2,2-pentafluoropropane (HCFC-225ca) (CAS No. 422-56-0). (xxxiv) 1,3-dichloro-1,1,2,2,3-pentafluoropropane (HCFC-225cb) (CAS No. 507-55-1). (xxxv) 1,1,1,2,3,4,4,5,5,5-decafluoropentane (HFC 43-10mee) (CAS No. 138495-42-8). (xxxvi) Difluoromethane (HFC-32) (CAS No. 75-10-5). (xxxvii) Ethyl fluoride (HFC-161) (CAS No. 353-36-6). (xxxviii) 1,1,1,3,3,3-hexafluoropropane (HFC-236fa) (CAS No. 690-39-1). (xxxix) 1,1,2,2,3-pentafluoropropane (HFC-245ca) (CAS No. 679-86-7). (xl) 1,1,2,3,3- pentafluoropropane ( HFC-245ea) (CAS No. 24270-66-4). (xli) 1,1,1,2,3- pentafluoropropane (HFC-245eb) (CAS No. 431-31-2). (xlii) 1,1,1,3,3- pentafluoropropane (HFC-245fa) (CAS No. 460-73-1). (xliii) 1,1,1,2,3,3-hexafluoropropane (HFC-236ea) (CAS No. 431-63-0). (xliv) 1,1,1,3,3-pentafluorobutane (HFC365mfc) (CAS No. 406-58-6). (xlv) Chlorofluoromethane (HCFC-31) (CAS No. 593-70-4). (xlvi) 1,2-dichloro-1,1,2-trifluoroethane (HCFC-123a) (CAS No. 354-23-4). (xlvii) 1-chlor-1-fluoroethane (HCFC-151a) (CAS No. 1615-75-4). (xlviii) 1,1,1,2,2,3,3,4,4-nonafluoro-4-methoxy-butane (C4F9OCH3 or HFE-7100) (CAS No. 163702-07-6). (xlix) 2-(difluoromethoxymethyl)-1,1,1,2,3,3,3-heptafluoropropane (CAS No. 163702- 08-7). (l) 1-ethoxy-1,1,2,2,3,3,4,4,4-nonafluorobutane (C4F9OC2H5 or HFE-7200) (CAS No. 163702-05-4). (li) 2-(ethoxydifluoromethyl)-1,1,1,2,3,3,3-heptafluoropropane (CAS No. 163702-06- 5). (lii) Methyl acetate (CAS No. 79-20-9). (liii) Perfluorocarbon compounds that fall into the following classes: (A) Cyclic, branched, or linear, completely fluorinated alkanes. (B) Cyclic, branched, or linear, completely fluorinated ethers with no unsaturations. (C) Cyclic, branched, or linear, completely fluorinated tertiary amines with no unsaturations. (D) Sulfur-containing perfluorocarbons with no unsaturations and with sulfur bonds only to carbon and fluorine. (liv) Methylene chloride (CAS No. 75-09-2). (lv) 1,1,1,2,2,3,3-heptafluoro-3-methoxy-propane (n-C3F7OCH3, HFE-7000) (CAS No. 375-03-1). (lvi) 3-ethoxy-1,1,1,2,3,4,4,5,5,6,6,6-dodecafluoro-2-(trifluoromethyl) hexane (HFE 7500) (CAS No. 297730-93-9). (lvii) 1,1,1,2,3,3,3-heptafluoropropane (HFC 227ea) (CAS No. 431-89-0). (lviii) Methyl formate (HCOOCH3) (CAS No. 107-31-3). (lix) T-butyl acetate (CAS No. 540-88-5). (lx) 1,1,1,2,2,3,4,5,5,5-decafluoro-3-methoxy-4-trifluoromethyl-pentane (HFE-7300) (CAS No. 132182-92-4). (lxi) Dimethyl carbonate (CAS No. 616-38-6). (lxii) Propylene carbonate (CAS No. 108-32-7). (lxiii) 2,3,3,3-tetrafluoropropene (HFO–1234yf) (CAS No. 754-12-1). (lxiv) Trans-1,3,3,3-tetrafluoropropene (HFO–1234ze) (CAS No. 29118-24-9). (lxv) HCF2OCF2H (HFE-134) (CAS No. 1691-17-4). (lxvi) HCF2OCF2OCF2H (HFE-236cal2) (CAS No. 78522-47-1). (lxvii) HCF2OCF2CF2OCF2H (HFE-338pcc13) (CAS No. 188690-78-0). (lxviii) HCF2OCF2OCF2CF2OCF2H (H-Galden 1040X or H-Galden ZT 130 (or 150 or 180)) (CAS No. 188690-77-9). (lxix) Trans 1-chloro-3,3,3-trifluoroprop-1-ene (SolsticeTM 1233zd(E)) (CAS No. 102687-65-0). (lxx) 2-amino-2-methyl-1-propanol (AMP) (CAS No. 124-68-5). (lxxi) 1,1,2,2-Tetrafluoro-1,-(2,2,2-trifluoroethoxy) ethane (HFE-347pcf2) (CAS No. 406-78-0). (lxxii) cis-1,1,1,4,4,4-hexafluorobut-2-ene (HFO-1336mzz-Z) (CAS No. 692-49-9). (lxxiii) trans-1,1,1,4,4,4-hexafluorobut-2-ene (HFO-1336mzz(E)) (CAS No. 66711-86- 2). The methods described in R 336.2004 and R 336.2040 must be used for measuring volatile organic compounds for purposes of determining compliance with emission limits. Where a method also measures compounds with negligible photochemical reactivity, these negligibly-photochemical reactive compounds may be excluded as volatile organic compounds if the amount of the compounds is accurately quantified and the exclusion is approved by the department.