CARGOS POR PRUEBAS

A. Autoridad para Conducir Pruebas. La Junta podrá, cuando 10 crea necesario, llevar a cabo pruebas de funcionamiento de una facilidad de desperdicios sólidos peligroso 0 no peligrosos para determinar el grado y cantidad de contaminantes que se están descargando al ambiente, aire, agua 0 al terreno; el grado de cumplimiento con las condiciones del permiso, 0 cumplimiento con este reglamento. PARTE X - REGLA 1002 B. Procedimiento para las Pruebas. En tal caso, la Junta notificará al dueño u operador de la facilidad de desperdicio sólido peligrosos de sus intenciones, y solicitará aquellos equipos 0 accesorios necesarios para llevar a cabo las pruebas. C. Gastos por Pruebas. El dueño u operador de la facilidad de desperdicio sólido peligroso 0 no peligroso deberá pagar los cargos por la prueba de funcionamiento. D. Procedimientos para el Pago de los Gastos por Pruebas. Después de completar las pruebas, el dueño u operador de una facilidad de desperdicio sólido peligroso 0 no peligroso será notificado por escrito, por la Junta, de los cargos 0 gastos por las pruebas dentro de treinta (30) días de dicha notificación resultará en la cancelación de cualquier solicitud 0 permiso para operar la facilidad. PARTE X - REGLA 1002 E. Copias de los Resultados de las Pruebas. Al pagar los cargos 0 gastos incurridos al conducir las pruebas de funcionamiento, el dueño u operador recibirá una (1) copia del informe de las pruebas de funcionamient. XI ANEJOS 34 97 Angret 21, 1587 9:05 A.LS ANEJO C-1 Appendix II EP Toxicity Test Procedures area is smaller or the particle size larger than specified above. the solid material shall be prepared for extraction by crushing. cutting or grinding the material so that it passes through a 9.5 mm (0.375 inch) sieve Dr. if the material ts in a single piece. by subjecting the material to the "Structural Integrity Procedure" described below. APPENDIX II-EP TOXICITY TEST PROCEDURES A. Extraction Procedure (EP) 1. A representative sample of the waste to be tested (minimum size 100 grams) shall be: obtained using the methods specified in Ap. pendix I or any other method capable of yielding a representative sample within the meaning of Part 260. [For detailed guidance on conducting the various aspects of the EP see "Test Methods for the Evaluation of Solid Waste, Physical/Chemical Methods" (incorporated by reference, see 1 260.11).) 2. The sample shall be separated into its component liquid and solid phases using the method described in "Separation Procedure" below. If the solid residue the obtained using this method totals less than 0.5% of the original weight of the waste, the residue can be discarded and the operator shall treat the liquid phase as the extract and proceed immediately to Step 8. 3. The solid material obtained from the Separation Procedure shall be evaluated for its particle size. If the solid material has a surface area per gram of material equal to, or greater than. 3.1 cm' or passes through a 9.5 mm (0.375 inch) standard sieve. the operator shall proceed to Step 4. If the surface 4. The solid material obtained in Step 3 shall be weighed and placed in an extractor with 16 times Its weight of deionized water. Do not allow the material to dry prior to weighing. For purposes of this test, an ac. ceptable extractor is one which will impart sufficient agitation to the mixture to not only prevent stratification of the sample and extraction fluid but also insure that all sample surfaces are continuously brought into contact with well mixed extraction fluid. 5. After the solid material and deionized water are placed in the extractor, the operator shall begin agitation and measure the pH of the solution in the extractor. If the pH is greater than 5.0, the pH of the solution shall be decreased to 5.0 I 0.2 by adding 0.5 N acetic acid. If the pH is equal to or less than 5.0. no acetic acid should be added. The pH of the solution shall be monstored. as described below. during the course of the extraction and If the pH rises above 5.2. 0.5N acetic acid shall be added to bring the pH down to 5.0 + 0.2. However. in no event shall the aggregrate amount of acid added to the solution exceed 4 ml of acid per gram of solid. The mixture shall be agitated for 24 hours and maintained at 20'- 40°C (68'-104'F) during this time. It is recommended that the operator monitor and adjust the pH during the course of the ex. traction with a device such as the Type 45-A pH Controller manufactured by Chemtrix. Inc., Hillsboro, Oregon 97123 or its equivalent. in conjunction with a metering pump and reservoir of 0.5N acetic acid. If such a system is not available, the following manual procedure shall be employed: (a) A pH meter shall be calibrated in accordance with the manufacturer's specifica. tions. (b) The DH of the solution shall be checked and, if necessary. 0.5N acetic acid shall be manually added to the extractor until the pH reaches 5.0 = 0.2. The pH of the solution shall be adjusted at 15, 30 and 60 minute intervals. moving to the next longer interval If the pH does not have to be adjusted more than 0.5N pH units. (c) The adjustment procedure shall be continued for at least 6 hours. (d) If at the end of the 24-hour extraction period, the pH of the solution is not below 5.2 and the maximum amount of acid (4 ml per gram of solids) has not been added. the pH shall be adjusted to 5.0 + 0.2 and the extraction continued for an additional four hours, during which the pH shall be adjusted at one hour intervals. 6. At the end of the 24 hour extraction period. deionized water shall be added to the extractor in an amount determined by the following equation: These methods are also described in "Samplers and Sampling Procedures for Hazardous Waste Streams." EPA 600/2-80- 018, January 1980. *The percent solids is determined by drying the filter pad at 80°C until it reaches constant weight and then calculating the percent solids using the following equation: Percent solids = V=(20)(W)-16(W)-A V=ml deionized water to be added W=weight in grams of solid charged to ex. tractor of 0.5N acetic acid added during extraction 7. The material in the extractor-shall be separated into its component Hould and solid phases as described under "Separation Procedure." 8. The liquids resulting from Steps 2 and shall be combined. This combined liquid 10: the waste itself if 11 has less than is percent solids. as noted in step 2) is the extract and shall be analyzed for the presence of any of the contaminants specified in Table I of 261.24 using the Analytical Procedures designated below. Separation Procedure Equipment: A filter holder. designed for filtration media having a nominal pore size of 0.45 micrometers and capable of applying a 5.3 kg/cm2( psi) hydrostatic pressure to the solution being filtered. shall be used For mixtures containing nonabsorptive solids, where separation can be effected without imposing a 5.3 kg/cm' pressure dif. ferential, vacuum filters employing a 0.45 micrometers filter media can be used. (For further guidance on filtration equipment or procedures see "Test Methods for Evaluating Solid Waste Physical/Chemical Methods" incorporated by reference. see 260.11). Procedure: (1) Following manufacturer's directions. the filter unit shall be assembled with & filter bed consisting of a 0.45 micrometer filter membrane. For difficult or slow to filter mixtures a prefilter bed consisting of the following prefilters in increasing pore size (0.65 micrometer membrane. fine glass fiber prefilter. and coarse glass fiber prefilter) can be used. (ii) The waste shall be poured into the filtration unit. (iii) The reservoir shall be slowly pressurized until liquid begins to flow from the filtrate outlet at which point the pressure in the filter shall be immediately lowered to 10-15 psig. Filtration shall be continued until liquid flow ceases. (iv) The pressure shall be increased stepwise in 10 psi increments to 75 paig and fil. tration continued until flow ceases or the pressurizing gas begins to exit from the filtrate outlet. (v) The filter unit shall be depressurized. the solid material removed and weighed and then transferred to the extraction appara- LUS, or. in the case of final filtration price analysis. discarded. Do not allow the mater a) retained on the filter pad to dry prior to weighing. (vi) The liquid phase shall be stored at 4°C for subsequent use in Step 8. 'This procedure is intended to result in separation of the "free" liquid portion of the waste from any solid matter having a particle size >0.45 µm. If the sample will not filter. various other separation techniques can be used to aid in the filtration. As described above. pressure filtration is employed to speed up the filtration process. This does not alter the nature of the separation. If liquid does not separate during fil. tration. the waste can be centrifuged. If sep. aration occurs during centrifugation. the liquid portion (centrifugate) is filtered through the 0.45 µm filter prior to becoming mixed with the liquid portion of the waste obtained from the initial filtration. Any material that will not pass through the filter after centrifugation is considered a solid and is extracted (weight of ped + solid) - (tare weight of pad) weight of sample X 100 B. Structural Integrity Procedure Equipment: A Structural Integrity Tester having a 3.18 cm (1.25 in.) diameter hammer weighing 0.33 kg (0.73 lbs.) and having a free fall of 15.24 cm (6 in.) shall be used. This device is available from Associated Design and Manufacturing Company, Alex. andria, VA 22314. as Part No. 125, or It may be fabricated to meet the specifications shown in Figure 1. Procedure shall be cut from the block having the dimensions of a 3.3 cm (1.3 in diameter X 7.1 cm (2.8 in.) cylinder. For a fixated waste. samples may be cast in the form of a 3.3 cm (1.3 in.) diameter X 7.1 cm (2.8 in.) cylinder for purposes of conducting this test. In such cases. the waste may be allowed to cure for 30 days prior to further testing. 1. The sample holder shall be filled with the material to be tested If the sample of waste is a large monolithic block. a portion 2. The sample holder shall be placed into the Structural Integrity Tester then the hammer shall be raised to its maximum height and dropped. This shall be repeated fifteen times. 3. The material shall be removed from the sample holder. weighed and transferred to the extraction apparatus for extraction Analytical Procedures for Ancissing Extract Conteminants The test methods for analyzing the extract are as follows: 1. For arsenic. barium. cadmium. chromium. lead. mercury. selenium. silver. endrin. lindane. methoxychlor. toxaphene 2.4- D2.4-dichlorophenoxyacetic acid) or 2.4.5- TP [2.4.5-trichlorophenoxypropionid acid): "Test Methods for the Evaluation of Solid Waste. Physical/Chemical Methods" (incorporated by reference, see $ 260.11). 2. [Reserved] For all analyses the methods of standard addition shall be used for quantification of species concentration. COMBINED WEIGHT 33Kg 1.73lb) (3.15cm) 11.25") 15.25cm (6") SAMPLE ELASTOMERIC" SAMPLE HOLDER 7.1cm 12.8" 3.3cm (1.3") 9.4cm 13.7" *ELASTOMERIC SAMPLE HOLDER FABRICATED OF MATERIAL FIRM ENOUGH TO SUPPORT THE SAMPLE Figure 1 COMPACTION TESTER [Appendix II] ANEJO C-2 Appendix III Chemical Analysis Test Methods APPENDIX III-CHEMICAL ANALYSIS TEST METHODS Tables 1. 2. and 3 specify the appropriate analytical procedures. described in "Test Methods for Evaluating Solid Waste, Physical/Chemical Methods." incorporated by reference. see $ 260.11) which shall be used to determine whether a sample contains a given Appendix VII or VIII toxic constituent. Table 1 identifies each Appendix VII or VIII organic constituent along with the ap. proved measurement method. Table 2 identifies the corresponding methods for inor ganic species. Table 3 summarizes the contents of SW-846 and supplies specific sec. tion and method numbers for sampling and analysis methods Prior to final sampling and analysis method selection the analyst should consult the specific section or method described in SW-846 for additional guidance on which of the approved methods should be employed for a specific sample analysis situation. TABLE 1.-ANALYSIS METHODS FOR ORGANIC CHEMICALS CONTAINED IN SW-846 [Amended by 50 FR 1999. January 14, 1985: revised by 50 FR 42942. October 23. 1985: amended by 51 FR 5330. February 13. 1986: 51 FR 6541, February 25. 1986] Compound Milhod No Acetonitrile 8030 8240 Acroider. 8030. 8240 Acrylamide 8015. 8240 Acrylonitrie 8030. 8240 2-Amano-I-methylibenzene (c-Toluidine) 8250 (p-Toluidine)- 8250 Aniline 6250 Benzene 8020. 8024 Benzfaianthracene 8100.8250 8310 Benzo(s)pyrene $100,8250 8310 Benzotrichloride 8120,8250 Benzyl chloride 8120,8250 Benzo(b)fluoantheria 8100,8250 8310 Bs/2-chioroethoxymethane) 8010.8240 Bis(2-chioroethyljether 8010,8240 Bis(2-chioroisopropyliether 8010,8240 Carbon disulfide 8015,8240 Carbon tatrachioride 8010,8240 Chiordane 8080.8250 Chionnated dibenzodioxins (Removed) Chlorinated biphenyts 8000,8250 Chiorinated dibenzo-p-dioxins 6280 Chiorinated dibenzofurans 8010,8280 Chioroacetaldehyde 8010.8240 Chiorobanzene 8020.8240 Chicroform 8010,8240 Chioromethane 8010.8240 2-Chiorophenol 8040,8250 Chysene 8100,8250. 8310 Creosots 6100,8250 Crescl(s) 8040,8250 Cresylic Acid(s) 8040,8250 Dichiorobenzene(s) 8010, 8120 8250 Dichiarosthane(s) 8010,8240 Dichioromethane 8010,8240 Dichiorophenoxyscetic acid 8150,8250 Dichioropropenol 8120,8250 2.4-Dimethy/phenol 8040,8250 Dinitrobanzene 8090,8250 4.6-Dinitro-o-oresal 8040.8250 2.4-Dinitrotoluene 8090. 8250 2.6-Dinitrotoiuene 8060 or 8250 Table 1.-Analysis Methods for Organic Chemicals Contained in SW-846-Continued Table 1.-Analysis Methods for Organic Chemicais Contained in SW-846- Continued Compound Method No Endrin BOBC. 825C 2-Emoxyethano 8030. 8240 Emoletne 8015. 8240 Ethylene dipromide 8010.8240 Formatoshyde 8015. 8240 Formic acid 8250 Heotachio 8080. 8250 Hexachiorobenzene 8120.8250 mexachiorobutadiene 8120. 8250 Hexachiorosthane 8010.8240 Hexachtorocyciopentadiene 8120. 8250 Lindane 6080. 8250 Maleic anhydride 1250 Methano 8010 5240 Methomy 8250 Methyl othyl ketone 8015. 8240 Methyt isobuty katone 8015 6240 Naphthalene 8100. 8250 Naphthoguinone 8090. 8250 Nitrobenzene 8090. 8250 2-Nitropropane 8030. 8240 4-Nitropheno 8040. 8240 Paraldehyde (trimer of acetaldehyde 8015. 8240 Pentachioropheno 8040. 8250 Phenol 8040. 8250 Phorate 8140 Phosphorodithic acid esters 8140 Phthalic anhydride 8090. 8250 2-Picoline 8090. 8250 Pyridine 8090. 8250 Tetrachiorobenzene(s) 8120 8250 Tetrachlorosthana(s) 6010. 6240 Tetrachiorosthens 8010. 8240 Tetrachiorophenol 8040. 8250 Toluens 8020. 8024 Toluenediamine 8250 2.4-Toluenadiamme 8250 2.6-Toluenediamins 8250 3.4-Toluensdiamme 8250 Compound Method No Toluene disocyanate(s) c250 Toxaphene 8080. 8250 Trichioroethane 8010 B24C 8010 8240 Tnchiorofuorometnane 8010 8240 Trichioropnenol(s) 8040. 825C 2.4.5-Tnichlorophenoxy propionic acid 8150 8250 Trichloropropane 8010. 824C Vinyl chloride 8010. 8240 Vinylidene chioride 8010. 824C Xylene 8020. 8240 Analyne for phehanthrene and carbazole if these are present E a ratio between 1.4:1 and 5:1 crecsote should be considered presem. TABLE 2-ANALYSIS METHODS FOR INORGANIC CHEMICALS CONTAINED IN SW-846 Second First edition Compoune edition mathod(s) method(s: Antimon 8.50 7040 7041 Arsent: 8.51 7060, 7061 Banum 8.52 7080, 7081 Cadmium 8.53 7090. 7091 Chromium 8.54 7190. 7191 Chromum Mexavaten: 8.545. 6.546 7195 7196 6.547 7197 Lead 8.56 7420 7421 Mercury 8.57 7470. 7471 Nickel 6.58 7520. 7521 Selenium 8.59 7740. 7741 Sever 6.50 7760. 7761 Cyanides 8.55 9010 Total Organic Halogen 8.66 9020 Suffices 6.67 9030 TABLE 3-SAMPLING AND ANALYSIS METHODS CONTAINED IN SW-846 Fest adition Second adition Title Section Method Section Method No No No. No Sampling of Soled Wastes 1.0 1.0 Development of Appropriate Sampling Plans 1.0 1.1 Regulatory and Scientific Objectives 1.0-2 11.1 Fundamental Statistical Concepts 1.0-3 1.1.2 Basic Statistical Strategies 1.0-7 1.1.3 Simple Random Sampling 1.1.3.1 Stratified Random Sampling 1.1.3.2 Systematic Random Sampling 1.1.3.3 Special Considerations 1.0-7 Composite Sampling 1.1.4.1 Subsampking 1.1.4.2 Cost and LOSS Functions 1.1.4.3 Implementation of Sampling Plan 1.0-7 1.2 Selection of Sampling Equipment 1.2.1 Composite Liquid Waste Sampler 3.2.1 1.2.1.1 Weighted Bottle 322 1.2.1.2 1.2.1.3 Dipper a.2.3 Thist 3.2.4 1.2.1.4 Trier 325 1.2.1.5 3.2.6 1.2.1.6 Auger Scoop and Shovel 3.2.7 1.2.1.7 Selection of Sample Containers 33 1.2.2 Processing and Storage of Samples 3.3 1.2.3 Documentation of Chain of Custody 2.0 1.3 Sample Labels 20-1 1.3.1 Sample Seals 2.0-3 1.3.2 1.3.3 Field Log Book 2.0-5 TABLE SAMPLING AND ANALYSIS METHODS CONTAINED IN SW-846-Continued First ednor Second edition Title Section Method Section Method No No No No Chain-of-Custody Pecord 2.0-6 134 Sample Analysis Request Shee: 20-9 1.3.5 Sample Delivery to Laboratory 20-10 136 Shipping of Samples 20-10 1.3.7 Receipt and Logging of Sample 20-12 1.3 E Assignment of Sample for Analysis 20-13 135 Sampling Methodology 30 14 Containers 3.2-2 1.4.1 Tanks 3.2-2 1.4.2 Wasis Pues 3.2-2 143 Landfills and Lagoons 3.2-2 144 Waste Evaluation Procedures 20 Characteristics of Hazardous Waste 21 a 40 21.1 Pensky-Martens Closed-Cup Method 41 211 1010 Setaflash Closed-Cup Method 41 211 1020 Corrosivity 5.0 212 Corrosivity Toward Steel 5.3 212 1110 Reactivity 6.0 2.1.3 Extraction Procedure Toxicity 7.0