Extraction Procedure Toxicity Test

17.1. 7.2. 7.5 Method and Structural Integrity Test 74 2.14 1310 Sample Workup Techniques 40 Inorganic Techniques 649 41 Acid Digestion for Flame AAS 41 3010 Acid Digestion for Furnace AAS 4.1 3020 Acid Digestion of Oil, Grease or Wax 849-5 41 3030 Dissolution Procedure for Oil. Grease or Wax 6.49-8 Alkahne Digestion 8.0 8.458 4.1 3060 Organic Techniques 8.0 4.2 Separatory Funnal Liquid-Liquid Extraction 9.0 9.1 4.2 3510 Continuous Liquid-Liquid Extraction 9.0 9.01 4.2 3520 Acid-Base Cleanup Extraction 8.0 8.84 4.2 3530 Soxhiet Extraction 8.0 8.86 4.2 3540 Sonication Extraction 8.0 8.85 4.2 3550 Sample Introduction Techniques 5.0 Headspace 8.0 8.82 5.0 5020 Purge-and-Trap 8.0 8.83 5.0 5030 inorganic Analytical Methods 8.0 7.0 Antimony. Flame AAS 8.0 8.50 7.0 7470 Antimony Furnace AAS 8.0 8.50 7.0 7471 Arsenic. Flame AAS 8.0 8.51 7.0 7060 Areanic Furnace AAS 8.0 8.51 7.0 7061 Banum Flame AAS 6.0 8.52 7.0 7080 Banum Furnace AAS 8.0 8.52 7.0 7081 Cadmum. Fiame AAS 8.0 8.53 7.0 7130 Cadmium. Furnace AAS 8.0 8.53 7.0 7131 Chromium Flame AAS 8.0 8.54 7.0 7090 Chromam Furnace AAS 8.0 8.54 7.0 7191 Chromium Hexavalent Coorectoriation 8.0 8.545 7.0 7195 Chromium, Makevalent Colonmatic 6.0 8.546 7.0 7196 Chromum. Hexavalent Chelation 8.0 8.547 7.0 7197 Lead. Flame AAS 8.0 8.56 7.0 7420 Lead Furnace AAS 8.0 8.56 7.0 7421 Mercury Cold Vapor, Liquid 6.0 8.57 7.0 7470 Mercury. Cold Vapor, Solid 6.0 0.57 7.0 7471 Nickel. Flame AAS 8.0 8.58 7.0 7520 Nickel, Furnace AAS 8.0 8.58 7.0 7521 Selenium. Flame AAS 8.0 8.59 7.0 7740 Selenium, Gaseous Hydride AAS 8.0 8.59 7.0 7741 Silver, Flame AAS 8.0 8.60 7.0 7760 Silver, Furnace AAS 8.0 8.60 7.0 7761 Organic Analytical Methods 6.0 6.0 Gas Chromatographic Methods 8.0 6.1 Halogenated Volatile Organics 8.0 8.01 6.1 8010 Nonhalogenated Volatile Organics 6.0 8.01 6.1 8015 Aromatic Volatile Organics 6.0 8.02 0.1 6020 Acrolein, Acrytonitric, Acetonitrite 6.0 8.03 8.1 6030 Phenois 8.0 8.04 6.1 8040 Phthalate Esters 8.0 8.06 6.1 6060 Orgenochtonne Pesticides and PCBs 6.0 8.08 8.1 8080 Nitroaromatics and Cyclic Ketones 8.0 8.09 6.1 8090 Polynuclear Aromatic Hydrocarbons 0.0 8.10 6.1 8100 Chionnated Hydrocarbons 6.0 8.12 8.1 6120 Organophosphorus Pesticides 8.0 8.22 8.1 8140 Chionnated Herbicides 6.0 8.40 8.1 8150 [Appendix III) TABLE 3-SAMPLING AND ANALYSIS METHODS CONTAINED IN SW-846-Continued First adition Second editor Title Section Method Section Method No No No No Gas Crromatographic/Mass Spectroscopy Methods (GC/MS 5.0 8.2 GC/MS volaties 8.0 6.24 82 8240 GC/MS Packed Column 80 0.25 8.2 8250 GC/MS Servi-Volaties Capiliary 8.0 8.27 8.2 627C Analysis o' Chiorinated Dioxins and Disenzaturans 8.2 8280 High Performance Louid Chromatographic Methods (HPLC) BC 6.3 Polynucles: Aromatic Hydrocarbons B.O B10 8.3 8310 Miscellaneous Analytical Methods B.C 9.0 Cyanide. Total and Amenable to Chiorination 80 8.55 9.0 9010 Total Organic Helogen (TOX 80 8 66 90 9020 Sulfices 6.0 867 90 9031 pri Measurement 50 52 80 9040 Quality Control/Quality Assurance 10.0 101 introduction 10.0 10.1 Program Design 10.0 10.2 Sampling 10.0 10.3 Analysis 10.0 10.4 Date Handing 10.0 105 See specific metal. ANEJO C-3 Appendix VIII Hazardous Constituents In the ..eantime. however. both the corrections 10 the existing appendix and the revised appendix are published for the convenience of our subscribers.] Beryllium and compounds N.O.S.* Hazardous Constituents Acetic acid. 2.4.5-trichlorophenoxy- salts and esters (2.4,5-T. salts and esters) [Corrected by 51 FR 28297. August 6. 1986) Acetonitrile (Ethanenitrile) Acetophenone (Ethanone. 1-phenyl) 3-(alpha-Acetonylbenzyl)-4 hydroxycoumarin and salts (Warfarin) 2-Acetylaminofluorene (Acetamide. N-(9H- fluoren-2-yl)-) Acetyl chloride (Ethanoyl chloride) 1-Acetyl-2-thiourea (Acetamide. N-(aminothioxomethyl)-) Acrolein (2-Propenal) Acrylamide (2-Propenamide) Acrylonitrile (2-Propenenitrile) Aflatoxins Aldrin (1,2,3.4,10.10-Hexachloro- 1.4,4a,5,8.8a-hexahydro-endo.exo- 1,4:5,8-dimethanonaphthalene) [Corrected by 51 FR 28297, August 6, 1986] Allyl alcohol (2-Propen-1-ol) Aluminum phosphide 4-Aminobiphenyl ([1.1-Biphenyl]-4-amine) 6-Amino-l.1a,2,8.8a.8b-hexahydro-8- (hydroxymethyl)-&a-methoxy-5-methylcarbamate azirino(2,3:3,4lpyrrolof1.2 alindole-4,7-dione, (ester) (Mitomycin C) (Azirino[2'3:3,4)pyrrolo(1.2-a)indole-47 dione. 6-amino-8-(((aminocarbonyl)oxy)methyl)-1,1a.2.8.8a.8b- hexahydro-8amethoxy-5-methy-) 5-(Aminomethyl)-3-isoxazolol (3(2H)-Isoxasolone. - 5-(aminomethyl)-) I Benzyl chloride (Benzene chioromethyo Bromoacetone (2-Propanone, 1-bromo-) Bromomethane (Methyl bromide) Bis(2-chloroethoxy)metnane (Ethane. 1.1 - (methylenebistoxy)lbisf2-chloro-1) Brucine (Strychnidin-10-one, 2.3-dimethoxy 4-Bromopheny) phenyl ether (Benzene, 1- bromo-4-phenoxy-) Bis(2-chloroethy)) ether (Ethane, 1.1 oxybis[2-chloro-)) 2-Butanone peroxide (Methyl ethy) ketone, peroxide: Bis(2-ethylhexyl) phthalate (1.2- Benzenedicarboxylic acid. bis(2-ethy). hexyl) ester) Butyl benzyl phthalate (1.2- Benzenedicarboxylic acid. buty) phenylmethy) ester) N.N-Bis(2-chloroethyl)-2-naphthiamine (Chiornaphazine) Bis(chloromethy)) ether (Methane. oxybis(chloro-)) Bis(2-chloroisopropyl) ether (Propane. 2.2- oxybis(2-chloro-)) 2-sec-Butyl-4.6-dinitrophenol (DNBP) (Phenol. 2,4-dinitro-6-(1-methylpropyl)-) Cadmium and compounds. N.O.S.* Calcium chromate (Chromic acid. calcium salt) Calcium cyanide Carbamic acid. ethyl ester [Appendix VIII revised by 46 FR 27476, May 20, 1981; corrected by 46 FR 29708, June 3, 1981; amended by 49 FR 5312, February 10. 1984: 50 FR 1999, January 14, 1985: 50 FR 42942, October 23, 1985; 51 FR 6541, February 25, 1986] [Corrected and revised by 51 FR 28297,' August 6, 1986] [Editor's note: EPA August 6, 1986, corrected various hazardous constituents in Appendix VIII and concurrently revised the appendix in its entirety (51 FR 28297). However, in revising the appendix, the agency did not include the corrections. Appendix VIII EPA told BNA that the corrections erroneously were omitted from the revised Appendix VIII and that a corrected version will be published. Barium cyanide Azaserine (L-Serine, diazoacetate (ester)) Barium and compounds, N.O.S." Auramine (Benzenamine, 4,4'- carbonimidoylbisIN.N-Dimethyl, monohydrochloride) Benz[c]acridine 3,4 Benzacridine) Arsenic trioxide (Arsenic (III) oxide) Benzialanthracene (1,2-Benzanthracene) Benzene, 2-amino-:-methyl (o-Toluidine) Benzene, 4-amino-1-niethyl Toluidine) Arsenic pentoxide (Arsenic (V) oxide) Benzene (Cyclohexatriene) Benzenearsonic acid (Arsonic acid, phenyl-) Benzene, dichloromethyl- (Benzal chloride) Benzenethiol (Thiophenol) Benzidine ([1.1-Biphenyll-4,4'diamine) Benso[blfluoranthene (2.3-Benzofluoranthene) Benzo[jlfluoranthene (7,8-Benzofluoranthene) Arsenic acid (Orthoarsenic acid) Benzola)pyrene (3,4-Benzopyrene) p-Benzoquinone (1.4-Cyclohexadienedione) Benzotrichloride (Bensene. trichioromethy). Arsenic and compounds. N.O.S.* Antimony and compounds. N.O.S.* Aramite (Sulfurous acid, 2-chloroethyl-, 2- [4-(1,1-dimethylethyl)phenoxyl-1- methylethyl ester) Amitrole (1H-1.2,4-Triazol-3-amine) Aniline (Benzenamine) [Corrected by 51 FR 28297. August 6. 1986] Carbon disulfide (Carbon bisulfide) Carbon oxyfluoride (Carbonyl fluoride) Chloral (Acetaldehyde, trichioro-) Chlorambuell (Butanoic acid. 4-[bis(2- chloroethyl)aminolbenzene-) Chlordane (alpha and gamma isomers) (4.7. Methanoindan, 1.2,4,5,6.7.8.8-octachloro- 3,4,7,7a-tetrahydro-) (alpha and gamma isomers) 4-Aminopyridine (4-Pyridinamine) [Corrected by 51 FR 28297, August 6, 1986) Chlorinated benzenes, N.O.S.* Chlorinated ethane. N.O.S.* Chlorinated fluorocarbons. N.O.S.* Chlorinated naphthalene. N.O.S.* Chlorinated phenol. N.O.S.* Chloroacetaldehyde (Acetaldehyde. chloro-) Chloroalkyl ethers, N.O.S." p-Chloroaniline (Benzenamine, 4-chloro-) Chlorobenzene (Benzene. chloro-) p-Chioro-m-cresol (Phenol. 4-chloro-3- methyl) 2-Chloro-1.3-butadiene (chloroprene) [Added by 49 FR 5312, February 10, 1984] Chlorobenzilate (Benzeneacetic acid. 4. chloro-alpha-(4-chlorophenyl)-alphahydroxy. ethy) ester) 1-Chloro-2.3-epoxypropane (Oxirane. 2. (chloromethyl)-) 2-Chloroethy) vinyl ether (Ethene. (2-chioroethoxy)-) Chloroform (Methane, trichloro-) Chioromethane (Methyl chloride) Chloromethy) methyl ether (Methane, chloromethoxy-) 2-Chloronaphthalene (Naphthalene betachloro-) 2-Chiorophenol (Phenol e-chioro-) 1-(o-Chlorophenyl)thioures (Thioures. (2- chiorophenyl)-) *The abbreviation N.O.S. (not otherwise specified) signifies those members of the general class not specifically listed by name in this appendix. 3-Chioropropene tallyl chioride) Dichioropropane N.O.S.* (Propane dichloro- N.O.S.", (Added by 49 FR 5312, February 10. 1984) 3-Chloropropionitrile (Propanenitrile, chioro-) Chromium and compounds. N.O.S.* Chrysene (1.2-Benzphenanthrene) Citrus red No. 2 (2-Naphthol. 1-((2,5- dimethoxyphenyl)azo]-) Coal tars Copper cyanide Creosote (Creosote, wood) Cresols (Cresylic acid) (Phenol, methyl-) Crotonaldehyde (2-Butenal) Cyanides (soluble salts and complexes). N.O.S.* Cyanogen (Ethanedinitrile) Cyanogen bromide (Bromine cvanide) Cyanogen chloride (Chlorine cyanide) Cycasin (beta-D-Glucopyranoside, (methy)- ONN-azoxy)methyl-) 2-Cyclohexyl-4.6-dinitrophenol (Phenol. 2. cyclohexyl-4.6-dinitro-) Cyclophosphamide (2H-1,3,2,-Oxazaphosphorine. (bis(2-chloroethyl)amino)-tetra hydro-, 2-oxide) Daunomycin (5.,12-Naphthacenedione, (8S- cis)-8-acetyl-10-1(3-amino-2.3.6-trideoxy)- alpha-L-lyxo-hexopyranosyl)oxy1-7.8.9.10- tetrahydro-6,8.11-trihydroxy-l-methoxy-) DDD (Dichlorodiphenyldichloroethane) (Ethane, 1.1-dichloro-2.2-bis(p-chiorophenyl)-) DDE (Ethylene. 1.1-dichloro-2.2-bis(4-chloropheny))-) DDT (Dichlorodiphenyltrichloroethane) (Ethane. 1.1.1-trichioro-2.2-bis(p-chlorophenyl)-) Diallate (S-(2.3-dichloroaliy)) disopropylthiocarbamate) Dibenzia.hlacridine (1.2.5.6-Dibenzacridine) Dibenzla,jjacridine (1.2.,7.8-Dibenzacridine) Dibenzia.hlanthracene (1.2.5.6-Dibenzanthracene) 7H-Dibenzoic.g)carbazole (3.4.5.6-Dibenzcarbazole) Dibenzofa.e]pyrene (1.2.4.5-Dibenzpyrene) Dibenzola.hlpyrene (1,2,5.6-Dibenzpyrene) Dibenzola.)pyrene (1.2.7.8-Dibenzpyrene) 1,2-Dibromo-3-chioropropane (Propane. 1,2. dibromo-3-chloro-) 1.2-Dibromoethane (Ethylene dibromide) Dibromomethane (Methylene bromide) Di-n-butyl phthalate Benzenedicarboxylic acid, dibuty) ester) o-Dichlorobenzene (Benzene. 1.2-dichloro-) m-Dichlorobenzene (Benzene, 1,3-dichloro-) p-Dichlorobenzene (Benzene, 1,4-dichloro-) Dichlorobenzene. N.O.S.: (Benzene, dichioro-, N.O.S.*) 3.3'-Dichlorobenzidine (f1,1-Biphenyl)-4,4'- diamine, 3.3-dichloro-) 1.4-Dichloro-2-butene (2-Butene, 1,4-dichloro-) Dichlorodifluoromethane (Methane, dichlorodifluoro-) 1.1-Dichloroethane (Ethylidene dichloride) 1.2-Dichloroethane (Ethylene dichloride) trans-1.2-Dichloroethene (1.2-Dichloroethylene) Dichloroethylene. N.O.S.* (Ethene, dichloro- N.O.S.*) 1.1-Dichloroethylene (Ethene, 1.1-dichloro-) Dichloromethane (Methylene chloride) 2.4-Dichlorophenol (Phenol. 2.4-dichloro-) 2.6-Dichlorophenol (Phenol. 2.6-dichloro-) 2,4-Dichlorophenoxyacetic acid (2,4-D). salts and esters (Acetic acid, 2,4-dichlorophenoxy- salts and esters) 1.2-Dichloropropane (Propylene dichloride) Dichioropropanol. N.O.S.' (Propanol. dich- 3- loro- N.O.S.") Disulfeton (O.O-diethy) S-12 Dichloropropene. N.O.S.* (Propene. dichloro- N.O.S.' (ethylthio)ethyll phosphorodithioate N.N'-Diethylhydrazine (Hydrazine. 1.2- diethyl) [Corrected by 51 FR 28297. August 6. 1986] O.O-Diethy) S-methyl ester of phosphorodithioic acid (Phosphorodithioic acid. O.O-diethy) S-methyl ester O,O-Diethylphosphoric acid. O-p-nitrophenyl ester (Phosphoric acid. diethyl p. nitrophenyl ester) Diethyl phthalate (1.2-Benzenedicarboxylic acid. diethyl ester) O.O-Diethy) O-2-pyrazinyl phosphoroth loate (Phosphorothioic acid, O,O-diethyl O-pyraziny) ester Diethyistilbesterol (4.4'-Stilbenediol, alpha,alpha-diethyl, bis(dihydrogen phosphate. (E)-) Dihydrosafrole (Benzene, 1.2-methylene dioxy-4-propyl-) 3.4-Dihydroxy-alpha-(methylamino)methyl benzy) alcohol (1.2-Benzenediol. 4-[1-hydroxy-2-(methylamino)ethyl)-) Diisopropylfluorophosphate (DFP) (Phosphorofluoridic acid. bis(1-methylethy)) ester) Dimethoate (Phosphorodithioic acid, 0,0 dimethyl S-[2-(methylamino)-2-oxoethyl) ester 3.3'-Dimethoxybenzidine ([1.1'-Biphenyl]- 4.4'diamine, 3-3-dimethoxy-) p-Dimethylaminoazobenzene (Benzenamine. N.N-dimethvi-4-(phenylazo)-) 7,12-DimethylbenzIa)anthracene (1,2-Benzanthracene. 7.12-dimethy)-) 3,3-Dimethylbenzidine ([1.1'-Biphenyl)-4,4 diamine. 3,3-dimethyl-) Dimethylcarbamoyl chloride (Carbamoy) chloride. dimethy)-) 2.4-Dimethylphenol (Phenol, 2.4-dimethyl-) Dimethyl phthalate (1,2- Benzenedicarboxylic acid, dimethyl ester) Dimethy) sulfate (Sulfuric acid. dimethyl ester) 1.2-Dimethylhydrazine (Hydrazine, 1.2-dimethyl.) (1.2- 1.1-Dimethylhydrazine (Hydrazine, 1.1-dimethyl.) 3,3-Dimethyl-1-(methylthio)-2-butanone O. ((methylamino) carbonylloxime (Thiofanox) alphaalpha-Dimethylphenethylamine (Eth. anamine. 1.1-dimethyl-2-phenyl-) Dinitrobenzene, N.O.S.* (Benzene, dinitro- N.O.S.") 4,6-Dinitro-o-cresol and salts (Phenol, 2.4- dinitro-6-methy). and salts) 2.4-Dinitrophenol (Phenol, 2.4-dinitro-) 2.4-Dinitrotoluene (Benzene, 1-methyl-2,4 dinitro-) 2.6-Dinitrotoluene (Benzene, 1-methyl-2,6. dinitro-) Di-n-octyl phthalate (1,2- Benzenedicarboxylic acid. dioctyl ester) 1.4-Dioxane (1.4-Diethylene oxide) Diphenylamine (Bensenamine, N-phenyl-) 1.,3-Dichloropropene (1-Propene 1.3-dichloro-) Dichlorophenylarsine (Phenyl dichloroarsine) Dieldrin (1.2.3.4.10.10-hexachloro-6.7-epoxy 1.4.4a.5.6.7.8.8a-octa-hydro-endo.exo 1.4:5.8-Dimethanonaphthalene) 1.2:3.4-Diepoxybutane (2.2-Bioxirane) Diethylarsine (Arsine, diethy)-) 1.2.Diphenylhydrazine (Hydrazine, 1.2-dipheny)- Di-n-propylnitrosamine (N-Nitroso-di-n-pro pylamine) 2,4-Dithiobiuret (Thioimidodicarbonis dia. mide) Endosulfan (5-Norbornene 2.3-dimethanol 1.4.5.6.7.7-hexachloro- cyclic sulfite Endrin and metabolites (1.2.3.4.10.10-heachloro-6.7-epoxv-1,4.4a.5.6.7.8.8a octahydro-endo.endo-1.4:5.8. dimethanonaphthalene and metabolites) Ethy) cyanide (propanenitrile) Ethylenebisdithiocarbamic acid. salts and esters (1.2-EthanedivIbiscarbamodithioic acid. salts and esters Ethylene glycol monoethy) ether (Exthanol. 2-ethoxy) [Added by 51 FR 6541. February 25, 1986] Ethyleneimine (Aziridine) Ethylene oxide (Oxirane) Ethylenethiourea (2-1midazolidinethione) Ethyl methacrylate (2-Propenoic acid. 2. methyl- ethyl ester) Ethyl methanesulfonate (Methanesulfonic acid, ethyl ester) Fluoranthene (Benzoli.k)fluorene) Fluorine 2-FTuoroacetamide (Acetamide. 2-fluoro-) Fluoroacetic acid. sodium salt (Acetic acid. fluoro. sodium salt) Formaldehyde (Methylene oxide) Formic acid (Methanoic acid) Glycidylaldehyde (1-propanoi-2,3-exoxy) [Corrected by 51 FR 28297. August 6, 1986] Halomethane. N.O.S.* Heptachlor (4,7-Methano-1H-indene 1.4.5.6.7.8.8-heptachloro-3a.4,7.7a tetrahydro-) Heptachlor epoxide Kalpha beta. and gamma isomers) (4.7-Methano-1H-indene 1,4,5.6,7,8.8-heptachloro-2,3-epoxy-3a,4,7.7. tetrahydro- alpha, beta and gamma isomers) Hexachlorobenzene (Benzene, hexachloro-) Hexachlorobutadiene (1,3-Butadiene, hexachloro-) [Corrected by 51 FR 28297. August 6, 1986]. Hexachlorocyclohexane (all isomers) (Lindane and isomers) Hexachlorocyclopentadiene (1,3-Cyclopentadiene, 1.2.3.4.5.5-hexachloro- Hexachlorodibenzo-p-dioxins Hexachlorodibenzofurans Hexachioroethane (Ethane, hexachloro-) [Corrected by 51 FR 28297, August 6, 1986) 1.2.3,4.10,10-Hexachloro-1.4.4a.5.8.8a- hexahydro-1.4:5.8-endo,endodimethanonaphthaiene (Hexachlorohexahydro-endo.endo dimethanonaphthalene) Hexachlorophene (2.2-Methylenebis(8,4,6- trichiorophenol)) Hexachloropropene (Propene, hexachloro-) [Corrected by 51 FR 28297, August 6, 1986] (Appendix VIII] Hexaethyl tetraphosphate (Tetraphos phone acid. hexaethy) ester) Hydrazine (Diamine: Hydrocyanic acid (Hydrogen cyanide) N-Methyl-N-nitro-N-nitrosoguanidine (Guanidine. N-nitroso-N-methyl-N'-nitro-) Methyl parathion (O.O-dimethy) O-14. nitrophenyl) phosphorothioate) Hydrofluoric acid (Hydrogen fluoride) Hydrogen sulfide (Sulfur hydride) Hydroxydimethylarsine oxide (Cacodylic acid) Indeno(1.2.3-cd)pyrene (1.10-(1.2) 1.4-Naphthoquinone (1.4-Naphthalenedione) Iodomethane (Methy) iodide) Iron dextran (Ferric dextran) Isocyanic acid. methy) ester (Methy) iso. Isobuty) alcohol (1-Propano). 2-methy)-) Isosafrole (Benzenc. 1.2.methylenedioxy-4. ally). ano-2H-cyclobuta|cd}-pentalene-2-one) ever. this hazardous constituent added 10 Appendix VIII.) Methylthiouracil (4-1H-Pyrimidinone. 2.3- dihydro-6-methy)-2-thioxo-) phenylene)pyrene cyanate 1-Naphthyl-2-thiourea (Thiourea. 1. naphthalenyl-) Kepone (Decachlorooctahydro-1,3,4-meth- Nitric oxide (Nitrogen (II) oxide) p-Nitroaniline (Benzenamine. 4-nitro-) [Editor's note: EPA August 6, 1986, corrected Nitrobenzene to read "Nitrobenzene" (51 FR 28297). However. this hazardous constituent was never added to Appendix VIII.] Lasiocarpine (2-Butenoic acid. 2-methyl- 7- [(2.3-dihydroxy-2-(1-methoxyethyl)-3 methyl1-oxobutoxy)methyl)-2,3,5,7a tetrahydro-1H-pyrrolizin-1-y) ester) N-Nitrososarco nitroso-) sine (Sarcosine, N-nitroso-) Lead and compounds. N.O.S." 5-Nitro-o-toluitine (Benzenamine. 2-methyl-5- nitro.) Maleic hydrazide (1,2-Dihydro-3.6-pyridazinedione) 7-Oxabicyclo|2.2.1Jheptane-2.3-dicarboxylc acid (Endothal) Pentachlorodibenzo-p-dioxins Nitrobenzine (Benzene, nitro-) Methacrylonitrile (2-Propenenitrile, 2- methy)-) Methanethio) (Thiomethanol) Nitrosopyrrolidine (Pyrrole. tetrahydro- N- Mustard gas (Sulfide. bis(2-chioroethyl]-) Naphthalene 1-Naphthylamine (alpha-Naphthylamine) 2-Naphthylamine (beta-Naphthylamine) Nicke) and compounds. N.O.S.* Nickel carbonyl (Nickel tetracarbonyl) Nickel cyanide (Nickel (II) cyanide) Nicotine and salts (Pyridine. (S)-3-(1-methyl- 2-pyrrolidinyl). and salts) [Corrected by 51 FR 28297, August 6. 1986] Lead acetate (Acetic acid. lead salt) Lead phosphate (Phosphoric acid, lead salt) Lead subacetate (Lead. bistacetato- O)tetrahydroxytri-) Nitrogen dioxide (Nitrogen (IV) oxide) Nitrogen mustard and hydrochloride salt (Ethanamine. 2-chloro-, N-(2-chloroethy))- N-methy). and hydrochloride salt) Maleic anhydride (2.5-Furandione) Octamethylpyrophosphoramide (Diphosphoramide. octamethyl-) Osmium tetroxide (Osmium (VIII) oxide) Nitrosamine. N.O.S.* N-Nitrosodiethanolamine (Ethanol, 2.2'- (nitrosoimino)bis-) Melphalan (Alanine. 3-ip-bis(2- chloroethy1)aminolphenyl-, L.) N-Nitrosodimethylamine (Dimethylnitrosamine) Methapyrilene (Pyridine, 2-[(2- dimethylamino)ethyl)-2-thenylamino-) Paraldehyde " 3.5-Trioxane 2.4.6-trimethyl-) Pentachlorodibenzofurans Parathion Phospnoromo acid. O.O-diethy) O-(p-nitrophenyl) ester Pentachlorobenzene (Benz.- H, pentachloro-) N-Nitrosodi-n-butylamine (1-Butanamine. N. butyl-N-nitroso-) N-Nitrosodiethylamine (Ethanamine. N-ethyl- N-nitroso-) 4-Nitroquinoline-1-ox1de (Quinoline. 4-nitro-1- oxide-) Metholmyl (Acetimidic acid, N- [(methylcarbamoyl)oxy)thiomethyl ester (Added by 51 FR 6541, February 25, 1986] N-Nitroso-N-ethylurea (Carbamide. N-ethyl- N-nitroso-) Pentachloroethane (Ethane. pentachioro-) Nitrogen mustard N-oxide and hydrochloride salt (Ethanamine. 2-chioro- N-12-chloroethyl)-N-methvl-N-oxide and hydrochloride salt) N-Nitrosomethylethylamine (Ethanamine. N. methyl-N-nitroso-) 2-Nitropropane (Propane. 2-nitro) Mercury fulminate (Fulminic acid, mercury salt) N-Nitroso-N-methylurea [Carbamide, N. methyl-N-nitroso-) Pentachloronitrobenzene (PCNB) (Benzene. pentachloronitro-) Malononitrile (Propanedinitrile) 4-Nitrophenol (Phenol. 4-nitro-) N-Nitroso-N-methylurethane (Carbamic acid. methylnitroso- ethyl ester) Pentachiorophenol (Phenol. pentachloro.) 2-Methylaziridine (1.2-Propylenimine) Methoxychlor (Ethane. 1.1.1-trichloro-2,2- bis(p-methoxyphenyl)-) [Corrected by 51 FR 28297, August 6. 1986) [Editor's note: EPA August 6, 1986, corrected 2-Methyl-2-(methylthio)propionaldehyde-o (methylcarbonyl)oxime to read "2-Methyl-2-(methylthio)propionaldehyde-o-(methylcarbonyl)oxime" (51 FR 28297). However, this hazardous constituent was never added to Appendix VIII.) Mercury and compounds. N.O.S.* N-Nitrosomethylvinylamine (Ethenamine. N. methyl-N-nitroso-) Perchioromethy) mercaptan (Methanesu):. envi chloride. trichloro-) Phenylenediamine (Benzenediamine) Phenylmercury acetate (Mercury. Phosgene (Carbonyl chioride) N-Nitrosomorpholine (Morpholine. N-nitroso- 3-Methylcholanthrene (Benz[jlaceanthrylene, 1.2-dihydro-3- methy)-) Nitroglycerine (1.2.3-Propanetriol. trinitrate) N-Nitrosonormicotine (Nornicotine, N. nitroso-) [Corrected by 51 FR 28297, August 6. 1986] N-Nitrosopiperidine (Pyridine, hexahydro-, N- nitroso-) Methyl chlorocarbonate (Carbonochloridic acid, methy) ester) Phenacetin (Acetamide. N-(4-ethoxypheny-}-) Phenol (Benzene. hydroxy-) [Editor's note: EPA August 6, 1986, corrected Nitrosopyrrolidine to read "N- Nitrosopyrrolidine" (51 FR 28297). How- 4,4-Methylenebis(2-chloroaniline) (Benzenamine. 4.4'-methylenebis-(2-chloro-) Methyl ethyl ketone (MEK) (2-Butanone) Methyl hydrazine (Hydrazine, methyl-) Phthalic acid esters. N.O.S.* (Benzene. 1.2- dicarboxylic acid. esters. N.O.S.*) Phthalic anhydride (1.2-Benzenedicarboxylic acid anhydride) 2-Methyllactonitrile (Propanenitrile, 2-hydroxy-2-methyl-) 2-Picoline (Pyridine. 2-methyl-) acetatophenyl-) Phosphorothioic acid. O.O-dimethyl O-jp- ((dimethylamino)sulfonyl)pheny)) ester (Famphur) N-Phenylthiourea (Thioures, phenyl-) Potassium cyanide Phosphine (Hydrogen phosphide) Methyl methacrylate (2-Propenoic acid, 2. methyl. methyl ester) Polychlorinated biphenyl. N.O.S.* Phosphorodithioic acid. O.O-diethyl S. [(ethylthio)methyl] ester (Phorate) 2-Methyl-2-(methylthio)propionaldehyde-o- (methylcarbony)) oxime (Propanal, 2. methyl-2-(methylthio)- O. [tmethylamino)carbonylloxime) Potassium silver cyanide (Argentate(1-). dicyano-, potassium) Methyl methanesulfonate (Methanesulfonic acid, methyl ester) Pronamide (3.5-Dichloro-N-(1.1-dimethyl-2- propynyl)benzamide) 1,3-Propane sultone (1.2-Oxathiolane, 2.2- dioxide) Propionic acid. 2- (2.4.5-trichlorophenoxy salts and esters (2.4.5-TP. Silvex. salts and esters) [Corrected by 51 FR 28297, August 6, 1986] n-Propylamine (1-Propanamine) Propylthiouracil (2,3-dihydro-6-propyl-2- thioxo-4(H)-pyrimidinone) [Corrected by 51 FR 28297, August 6, 1986] 2-Propyn-1-ol (Propargyl alcohol) Pyridine Reserpine (Yohimban-16-carboxylic acid. 11.17-dimethoxy-18-|(3.4.5- trimethoxybenzoyl)oxy). methyl ester) Resorcinol (1.3-Benzenediol) Saccharin and salts [1.2-Benzoisothiazolin-3- one. 1.1-dioxide. and salts) Mi-methylenedioxy Thalhe exide (Tnailium 1111, oxede Perchioromethyl mercaptan (Methanesul- Thallium (1) acetate (Acenc acid. thalium (I) fenyl chloride, trichloro-) (5) FR 28297, Seientum dioxide) salt) However. the former hazardous constitu- Selem I'm and compounds. NOS' Thallium (I) carbonate (Carbonic acid. emi was never added 10 Appendix VIII.) dithallium. {1) salt) Selenium sulfide (Sulfur selenide) Selenoures (Curbamimiduselenoie acid) Thallium (1) chloride Thallium (I) nitrate (Nitric acid. thallium (1) Trichloromethanethiol (Methanethio). Sliver and compounds. N.O.S.' salt) trichloro-) Silver cyenide Thallium selenite Trichloromonofiuoromethane (Methane. Sodium cyanide Thallium (1) sulfate (Suffuric acid. thallium (I) trichiorofluoro-) Streptozolocin (D-Glucopyranose. 2-deoxy-2- salt) 2.4.5-Trichlorophenol (Phenol. 2.4.5-trichloro-) {3-methyl-3-nitrosoureido)-) Thioacetamide (Ethanethiosmide) 2.4.6-Trichiorophenol (Phenol, 2.4.6-trichloro-) Sirontium sulfide Thiosemicarbazide Trichioropropane. N.O.S.* (Propane. Suychnine and salts (Strychnidin-10-one. and (Hydrazinecarbothioaniide) trichioro- N.O.S.*) salis) Thiourea (Carbamide thio-) 1.2.3-Trichioropropane (Propane. 1.2.3- 1.2.4.5-Tetrachloronenzene (Benzene. 1,2,4,5- Thiuram (Bis(dimethylthiocarbamoy) trichloro-) tetrachioro-) disulfide: 2.3.7.B-Tetrachlorodibenzo-p-dioxin (TCDD) O.O.O-Triethyl phosphorothioate Toluene (Benzene. methyl-) (Phosphorothioic acid, 0.0.0-triethyl ester) (Divenzo-p-dioxin. 2.3.7.8-tetrachloro-) Toluenediamine (Toluene. 2.5-diamine-) sym-Trinitrobenzene (Benzene. 1.3.5-trinitro-) Tetrachiorodibenzo-p-dioxins Tris(1-azridinyl) phosphine sulfide Tetrachlorodibenzofurans [Corrected by 51 FR 28297, August (Phosphine sulfide. tris(1-aziridiny)-) Tetrachloroethane. N.O.S.* (Ethane. 6, 1986] Tris(2.3-dibromopropyl) phosphate [1- tetrachioro- N.O.S.') 2.4-Toluenediamine Propanol. 2.3-dibromo-, phosphate) 1.1.1.2-Tetrachlorethane (Ethane. 1.1.1.2- Trypan blue (2.7-Naphthalenedisulfonic acid. 2.6-Toluenediamine tetrachloro-) 3,3'-[(3.3'-dimethyl(1.1'-biphenyl)-4.4- 1.1.2.2-Tetrachiorethane (Ethane. 1.1.2.2- 3.4-Toluenediamine djyl)bis(azo)]bis(5-amino-4-hydroxy tetrachioro-) Toluenediamine. N.O.S. tetrasodium salt) Tetrachloroethane (Ethene. tetrach- o-Toluidine hydrochloride (Benzenamine. 2- indecamethylenediamine, N.N'-bisloro-1 methyl-, hydrochioride) [Corrected by 51 FR 28297. August Tolylene diisocyanate (Benzene. 2.4-and 2.6- 2-chlorobenzyl)-. dihydrochloride (N.N'- disocyanatomethy)-) Undecamethylenebis (2-chiorobenzyla- 6. 1980} mine. dihydrochioride) Tetrachloromethane (Carbon tetrachloride) [Corrected by 51 FR 28297. August [Corrected by 51 FR 28297. August 2.3.4.6.-Tetrechlorophenol (Phenol. 2.3.4.6- 6. 1986] 6, 1986] tetrachioro-) Toxaphene (Camphene. octachloro-) Tetraethyldithiopyrophosphate fribromomethane (Bromotorm) Uracil mustard (Uracil 5-(bis(2- (Dithiopyrophosphoric acid. tetraethy!- 1.2.4-Trichlorobenzene (Benzene, 1.2.4 chloroethyl)amino]-) ester) trichloro-) Vanadic acid. ammonium salt (ammonium Tetracthy lead (Piumbane. tetraethyl.) 1.1.1-Trichioroethane (Methyl chloroform) vanadate) Tetraethyipyrophosphate (Pyrophosphoric 1.1.2-Trichloroethane (Ethane. 1.1.2-trichioro-) Vanadium pentoxide (Vanadium (V) oxide) acide. tetraethy! ester) Trichloroethene (Trichloroethylene) Vinyl chloride (Ethene. chioro-) Tetranitrumethane (Methane, tetranitro-) [Editor's note: EPA August 6. 1986 Zinc cyanide Thallium and compounds. N.O.S.* corrected Trichloromethanethiol 10 read Zinc phosphide [Appendix VIII revised by 51 FR 28279. August 6. 1986] APPENDIX VIII.-HAZARDOUS CONSTITUENTS Chemical Chemical abstracts name abstracts No. Common name 76-05-8 Same 98-85-2 Acctoritive Ethenone, 1-pheny 53-96-3 Acetophenone 2-Aceryiaminofluorena Acetamide, N-9H-fluoren-2-yt 75-36-5 Same 591-08-2 Acetyl chioride Acctamide. 107-02-8 79-06-1 2-Propenal Acroiem 107-13-1 Activiance 2-Propenamide 2.Propenentrile 1402-68-2 Acrytonitric Aflatoxin 118-06-3 Attatoxes 309-00-2 Ald-carb Propanal, 1.4:5.6-Drnethanonapithalene. 2-methyl-2-(methythuo)- 46 Salpha Balpha 107-18-6 Aldnn 2-Propan-1-01 107-05-1 Alivi alcohol 1-Propane. 3-chioro 20850-73-8 Altyt chionde Same 92-67-1 Aluminum prosphide (1.1-Bphenyl)--amme 2763-96-4 4-Aminobionemy 3(2H)-itoxazolone. 5-(aminomethy) 504-24-5 4-Pyndweammene 61-82-5 #-Aminopyndine 1H-1.2.4-Tnazol-3-amwe 7803-55-6 AMERICA Vanadic acid. ammonium set 62-53-3 Ammonium vanadate Banzanamine 7440-96-0 Antine 140-57-B Antimony and compounds N.O.S.' Antimone Sulturous act 2-chiorocthyl- ester 7440-38-2 Aramite 7776-30-4 Arsenic and compounds N.O.S Arsenic Areanic acid AsH.O. 1303-28-2 Arsenic acid Arserve pentoxide Americ ande A&D 1327-53-3 Areanic caude A&D, 492-80-8 Arsenic a Benzamine, Authority APPEND WWW-HAZARDOUS CONSTITUENTS-Coninued Common name Chemica absument rame Azasence L-Seme diazoscetate 115-02-6 Banun and compounds NOS Barket 7440-39-3 Sarrum cyanade Same 542-62-1 Same 225-51-4 Benzia)anthracene Same 56-55-2 Benza chionge Benzene (dichioromethy) 98-87-3 Benzone Same 71-43 2 BCID Arsonic BDC pheny 96-05-5 Benzidine damne 92-87-: Benzolb)fuoranthene Benzfelacepnenanthryene 205-99-2 BenzoliDfuoranthene Same 205-62-3 Benzolaupyiene Same 50-32-8 p-Ber-zoquirione 106-51-6 Benzeirechlonge Benzene BB-07-7 Bevy chiode Benzene (chioromethy) 100-44-7 Beryflaum and compounds N.O.S. Beryllum 7440-41-3 Emane 1.1-Imethylenebesionyllo:s:2-cnorc 111-91-1 Bist?-chicroethy ether Ethane 11 111-44-4 ether Procane 2.2 oxybis 2-chore 39635-32-9 ether Methane. 542-88-1 prithalate and este 117-81-7 Bromoscetore 2-Procatione 1-bromo 598-31-2 Bromotom Metnane tobromo 75-25-2 4-Bromicpheny phenvi ether Benzene 1-brome-4-prenon 101-55-3 brooke Struchndm-10-one 2.3-amemon 357-57-3 Buty benzy: phthalate 1,2-Senzenedicarbozyhc and buy phenymethy aster 85-68-7 Cacodync acid Arserve acid demetny. 75-60-5 Cadmium and compounds. N.O.S.¹ Cammun 7440-43-9 Calcium chromate Chromic acid, calcum sat. 13765-19-0 a Same 592-01-8 Carbor disultide Caroon Discline 75-15-0 Carbon oxyflunce Carbonic disconde 353-50-4 Carpon terachioride Metnane terrachions 56-23-5 Chica Acetaldenide the 75-87-6 Chiorambuck Benzeneoutancic and 305-03-3 Chlorgane sicha and gamma isomers 4.7-Methano-1H-indene 12 567.8.8-octachioro-2.33 1.7.7a-hexahyoro 57-74-8 Chionnated benzenes NOS Chionnated ethane NOS Chionrated fluorocarbons N.O.S Chicrinated naphthalene NOS Chorinated phenol. N.O.S Chiornaphazine 2-Naphthalename N.N-his/2-chroethyfi 494-03-1 Acetaidenyoe chioro 107-20-0 ethers NOS p-Chioroaniline Benzenaming <-chioro- 106-47-8 Chioroperzene Benzene. chioro- 106-90-7 Chioropenziiste Benzeneacetic acid 4-chioro-atpha-(4-chioronnenyl)-atpha-hydroy attry ester 510-15-6 p-Chioro-m-cresol Phenol 4-chioro-3-metri- 59-60-7 1-Choro-2,3-apoxypropane Chorane, (chloromethyfi- 106-89-8 2-Chioroethy a ether Ethene. (2-chioroethoxy) 110-75-8 Chicrotom Methane inchiore 67-66-3 Chloromethy methy) ether Metnane. chicromethoxy 107-30-2 bets-Chioronaphthaiene Naphalene 2-chioro 91-58-7 ©-Chioropneno Phenoi. 2-chioro- 95-57-8 1-(o-Chioropheny) thoures Thoures (2-chiorophenyfi- 5344-82- Chicroprene 2-Chloro-1,3-butediene 126-99-8 3-Chioropropionstrite Propanentrie 3-chioro 542-76-7 Chromium and compounds N.O.S.¹ Chromium 7440-47-3 Chrysene Same 218-01-9 Citrus red No 2 2-haphthalenol 1-[(2.5-dimethoxypheryiazc) 6358-53-8 Cost tars 8005-45-2 Copper cyanide Copper cvanide CuCh 544-92-3 Creosote Same 8001-58-9 Cresols (Cresylic acid) Phenol methyl- 1319-77-3 Crotonaldehyde 2-Butenal 4170-30-3 Cyanides (soluble salts and complexes) N.O.S. Cyanogen Ethanedmitrile 460-19-5 Cyanogen bromide Same 506-68-3 Cyanogen children Same 506-77-4 Cycasin beta-D-Glucopyranoside. (methyi-ONN-azoxymethy 14901-08-7 2-Cyclohexyi-4.6-dstrpphencr Phenol 2-cyclohexyl-4.6-dinero 131-89-5 Oyclophosphamide 2-1.3.2-Oxazaphosphorin--emne N.N-bis)2-chioroethy/)terahycro 2-oxide 50-18-0 2.4-D. salts and esters Acetic acid. (2.4-dichioraphenory) salts and esters 84-75-7 Dauncmyon 20630-81-3 Inhydroxy-1-mathoury 000 Benzene, 72-54-8 DDE Benzene 72-55-9 DOT Benezene. 50-29-3 Diskate and ester 2303-16-4 Dibenzia.h)acndine Same 226-36-8 Dibenzia:)amdine Same 224-42-0 Dibenz(a.h)anthracene Same 53-70-3 Same 104-59-2 192-65-4 Dibenzofa,h)pyrens Dibenzo[b.del)chrysens 189-64-0 Dibensoa:ovene Benzo[rsi)pentaphene 189-56-9 1.2-Dicromc-3-chioroprocane Propane 1.2-dioromo-3-chioro 96-12-6 Dibutylprithalate and dibuty ester 84-74-2 e-Dicntorobenzene Benzene 1.2-dichioro- 96-50-1 m-Dichioropenzene Benzene 1.3-dichioro 641-73-1 APPENDIX VIII.-HAZARDOUS CONSTITUENTS-Contnued Cherica Common name Chemical abstracts name No Benzene 1.4-dichioro- 106-46-7 Dichiorobenzane NOS benzene dichioro- 25321-22-6 3.3 -Dichiorotanzidine [1.1-Bpheny)-4,4-damne 3.3'-dichiore 91-94-1 4-Dichinro DUTOTE 2-Butens 1.4-dichioro- 764-41-0 Dichiorodifuorometnane Methane dichtorodifiuoro 75-71-5 1.2-Dichioroethviens Ethene. 1,2-dichioro-, (E) 156-60-5 Dechiorosthytone N.O.S Dichloroethylene 25323-30-2 1.1-Dichiorsethylene Ethere. 1.1-dichioro- 75-35-4 2.4-Dechiorophenol Phenol. 2.4-d-chioro- 120-83-2 2.6-Dichioropheno Phenol 2.6-dichloro- 87-65-0 Dichiorophenylarsine Arsonous dichionas. phenyl- 696-28-6 Dichioropropane, NOS' Propane, dichioro 26638-19-7 Dichioropropanol N.O.S Propanol dichiare 26545-73-3 Dichioropropene N.O.S.¹ 1-Propene dichioro- 26952-23-8 1.3-Dichioropropene 1-Propene 1.3-dichioro- 542-75-6 Dieldren 2.7:3.6-Dnethanonaphth(2.3-]oxen 60-57-1 1.2.3.4-Diepoxybutane 2.2'-Bioxire 1464-53-5 Diethviarsine Arsine, diethyl- 692-42-2 1,4 Diethyieneoinde 1.4 Dioxane 123-91-1 N.N'-Dietrylhydrazine Hydrazine. 1.2-deethry- 1615-80-1 O.O-Detriyi S-methylditmophosphate Phosphorodithic acid. O.D-diethyf S-methy ester 3286-58-2 Deathyl-p-nitro pnenyl phosphate Phosphone acid, diethyl-4-nitropherry1 ester 311-45-5 Diethytohthalate 1.2-Benzenedicarboxykc acid. diethyl ester 84-66-2 0.0-Diethy O-pyrazing phosphorothicate Phosphorothic acid, O.O-diethy! O-pyrazing ester 297-97-2 Diethylstilbestero Phenol, 56-53-1 Dihydrosatross 1.3 Benzodioxole, 5-propy- 94-58-6 3.4-Dihvgroxy-stpna-(methytamino)methy (+-)-1,2-Benzenediol, 4-[1-hydroxy-2-(mathylamano)ethyi). 329-65-7 benzyl alcohol DisopropyHluorophosphate(DFP) Phosphorofluoridic acid bre(1-methylethy) este: 55-81-4 Dimethoate Phosphorodithic acid. O,O-dimathy S-12 60-51-5 3.3-Dimemoxvbenzidne 3.3'-demethoxy 119-90-4 Benzanamine, N.N-demethy-4-(pnenyiazo) 60-11-7 7,12-DmnettvibenaIslanthraoene Benzielamhracene. 7.12-dimethy1 57-97-6 3.3 -Dmethivibenadine [1.1-Bphenyl)-4.4'-diarne 3.3'-dimethyl- 119-93-7 Demethvicartiamovi chioride Carbamic chloride, dimathyi- 79-44-7 1,1-Drmethyihyorazina Hydrazine. 1.1-dimethy)- 57-14-7 1,2-Demathylhydrazone Hydrazine 1,2-dimathyl- 540-73-8 alpha aipha-Dmsthylphenethylarene Benzensethanamine, alpha,alphe-dimethy- 122-09-8 2.4-Dimethylphenol Phenol, 2,4-dimethyl- 105-67-9 Dimethytphthelate 1.2-Benzenedicarboxyec acid. dimethy) ester 131-11-3 Dimethy suitate Sulfuric acid. demethy ester 77-78-1 Dintrobenzene N.O.S.' Benzene, diritto 26154-54-5 4.6-Dintro-o- cresol and salts Phenot, 2-mathyl-4.6-dinitro- and salts 534-52-1 2.4-Dintrophenot Phenoi, 2.4-dinaro- 51-28-5 2.4-Dintrotoluens Benzens, 1-mathyl-2.4-dinitro 121-14-2 2.6-Dinitro toluens Benzene, 2-methyl-1,3-dinaro- 606-20-2 Dinceeb Phenol, 2-(-mathrylpropyf)-4,6-dinero 88-85-7 Di-n-octyphthsiate 1.2-Benzenedicarboxytic acid, dioctyl ester 117-84-0 Diphenytamine Benzensmine, N-phenyl- 122-39-4 1.2-Diphenymydrazine Hydrazine. 1.2-diphenyl- 122-66-7 1-Propenamine, N-nitroso-N-propy- 621-64-7 Disultator Phosphorodithic acid, O-dethyl S-12-(ethyltwo)ethy1) ester 298-04-4 Treoimidodicarbonic diamide 541-53-7 Endosuman 6.9-Metnano-2,4,3-benzodioeathimpen 115-29-7 Endothel acid 145-73-3 Endrin 72-20-8 Ethyl carbemate (urethane) Carbamic acid. athyl ester 51-79-6 Ethyt cyenide Propenentrile 107-12-0 Ethytensbisdithiocartermc acid, selts and Carbamodithic and 1,2-ethanedryitie-, salts and esters 111-54-6 actors Ethylene dibromide Ethene, 1.2-dibromo 106-93-4 Ethylene dichioride Ethane. 1.2-dichioro- 107-06-2 Ethylene glycol monosthyl other Ethanol, 2-ethoxy- 110-80-8 Ethyleneimins Azindine 151-56-4 Ethylene courte Oxirane 75-21-8 Ethylenethwoures 96-45-7 Ethylidens dichioride Ethane, 1.1-dichloro- 75-34-3 Ethyl methacrytate 2-Propenoic acid, 2-methyl. ethyl ester 97-63-2 Ethylmethans sultoriste Methanesulfonic acid, ethyl ester 62-50-0 Famphis Phosphorothic and D-[4-[(dimethylaring) authorized phanyl) O.O-dimethyl eater 52-85-7 Fluoranthens Same 206-44-0 Fluonne Same 7782-41-4 Fluoroacetamide Acetamide, 2-Auoro- 640-19-7 and sodium salt Acetic acid, Buoro-, sodium salt 62-74-0 Formaldehyrie Same 50-00-0 Glycidytaldehyde Cauranscarboxysidehyde 765-34-4 Halomethane, N.O.S.' Haptachlor 4,7-Methano-1H-indene, 76-44-8 Heptacher epoxide bots and gamma isomers) 1024-57-3 Haxachloroberizens Benzene, hexachioro- 118-74-1 Hamachiorobutaciens 1,3-Butadiens, 1.1.2.3,4.4-hexachloro- 67-68-3 1.3-Oyclopentadiene, 1.2.2.4.5.5-haxachtorp 77-47-4 Hexachiorodiberzolurans Hexachiorosthane Ethane. hexechioro 67-72-1 Hakachiorophene Phenol. 70-30-4 Hexachtoropropene 1-Propene, hexachioro 1888-71-7 Mexsethyhatraphosphaia Tetraphosphone acid. healthy acter 767-58-4 Hydrazine Same 302-01-2 APPENDIX VIII.HAZAROOUS CONSTITUENTSContnued Common name Chemical abstracts name Chemica apstracts No Hydrogen cyange Hydrocyanic acid 74-90-8 Invoropen fuonde acid 7664 39-3 Hydropen suinde Same 7783-06-4 Indenol 2.3cdjpviene Same 193-39-5 Mon deter Same 9004-66-4 Isobuty sicoho 1-Propanol. 2-methy) 78-83-1 Isodnn tsosatrole 1.3-Benzodioxole 5-11-propeny) 120-58-1 Kepone 143-50-0 Lasiocaroine 2-Butencic and 2.3.5.7a tetrahydro-1H-pyrrolann-1- 303-34-4 y/ aster. Lead and compounds NO.S.' 7439-92-1 Lead aceise Acenc and lead(2) san 301-04-2 Lead prosonate Phosonone and lead(2+) salt 7446-27-1 Lead subacatate Lead bisiacetato-O)tetra/yoroxytn- 1335-32-6 Lingane Cyclohexane 1.2.3.4.5.6-Hexachioro- 58-89-9 Maled anhydride 2.5-Furancione 108-31-6 Maler: hydrazide 3.6-Pynoazmedione. 1.2-dinydro- 123-33-1 Matononam Propanedinitrue 109-77-3 Metorialar L-Phenvisianine, 4-bis(2-chiorpethyliameno). 148-82-3 Mercury furninate Fulminic acid. mercury(2+ sah 626-86-4 Mercury and compounds N.O.S Same 7439-97-6 Metnacry/on/trie 2-Propanentrile 2-methy- 126-96-7 Methapyniens 1.2-Ethanediamine 91-80-5 Methormy: Acetimidic acid. N-E(methyicarbamoyloxy)ne methy este: 18752-77-5 Methoxychier Benzene 1'-12.2.2-tnchioroethyhdene)(4-methoxy 72-43-5 Methy bromide Methane bromo- 74-83-9 Methy chlonge Methane. chioro- 74-87-3 Methvichiorocarbonste Carbonchloridic acid methy ester 79-22-1 Methy chiorotom Ethane 1.1.1-thchioro- 71-55-6 66-49-5 4'-Metrvienebrs(2-chioroaniine Benzenamine 4,4-methylenabis -chioro- 101-14-4 Methviene promide Methane, dioromo- 74-95-3 Methylene chronge Mathane dichioro 75-09-2 Metriy: attivi ketone (MEK) 2-Butanone 78-93-3 Merty strivt keione peroxide 2-Butanone perciase 1338-23-4 Methyl hydrazine Hydrazine methyl- 60-34-4 Methvi a Mathana. a 74-66-4 Methys a Methane, mocyanato- 624-83-9 Propenentrie, 2-hydroxy-2-methvi- 75-86-5 Methyl methacrylate 2-Propenoic acid. 2-methys. methyl ester 60-62-6 Mathy methanesultonate Methanesulfonic acid. methyl ester 06-27-3 Methyl parathion Phosphorothic acid, O.O-dimetnyl O-(4-nrtropnemy) ester 298-00-0 Methytthiourack 4(1H)-Pynmidinone, 2.3-dinydro-6-methyi-2-thoxo- 56-04-2 Mitornycin C Apnnol2 3:3.4)pyrroo(12-al indole-4.7-dione 50-07-7 methyl- MINNG Guaradine, N-msthy-N-nitio-N-ndroso 70-25-7 Mustard gas Ethane, 505-60-2 Nephthalene Same 91-20-3 1.4-Naphthoqumone 1,4-Naphthalenadione 130-15-4 alpha-Naphthytamme 1-Naphthaienamme 134-32-7 beta-Naphthytamine 2-Naphthalenamme 91-59-8 atpha-Nsphmyithiourez Thoughts 1-naphthalenyl- 06-88-4 Nicket and compounds N.O.S. Same 7440-02-0 Nickel carbonv. Nicket carbonyt, (T-4) 13463-39-3 Nicket cyanide Same 557-19-7 Nicotine and salts Pyridine, (S)-3-(1-methy-2-pymolidiny) and smits 54-11-6 Name oxide Nitrogen oxide NO 10102-43-9 p-Nitroane Benzenamine, 4-nitro- 100-01-8 Nitrobenzene Benzene. nitro- 96-06-3 Nitrogen dioxide Nitrogen oxide NO, 10102-44-0 Nitrogen mustard and hydrochlonde salt Ethenamine 2-chioro N-(2-chioroathyl)-N-mathyl and hydrochloride selt 51-75-2 Nitrogen mustard N-oxide and hydrochloride Ethanamine, 2-chtoro-N-(2-chsoroalthyl)--methy N-oxide, and hydrochloride selt 126-85-2 san Nitroglycenn 1.2.3-Propenetriol winitrate 56-63-0 p-Nitrophenol Phenot, 4-niro 100-02-7 2-Nitropropane Propers. 2-nitro- 79-46-0 Quincine. 4-nitro-1-code- 56-57-5 Nitrosamine, N.O.S.' 35576-91-1 N-Nitrosodi-n-butylamne 1-Butanamine. N-butyl-N-ratroso 924-16-3 N-Ntrosodiethanolamene Ethenol, 2.2 -(nitrosoimino)bis- 1116-54-7 N-Natroacchethylamme Ethanamine. N-sthyl-N-nutroso 55-18-5 N-Nitrosodimethylamme Methamine N-methyl-N-natroso 62-75-0 Urea. N-ethyl-N-nitroso- 750-73-9 Ethanemine, N-methyl-N-nitrose 10595-05-6 N-Neroso-N-methylylures Urea. N-methyl-N-ritroso 664-83-5 N-Nitroso-N-methyurathiane Carbamic acid. methyinitroso-, ethyl ester 615-53-2 Vinytamine, N-methyl-N-nitroso 4549-40-0 N-Nitrosomorpholine Merpholine, N-nitroso 50-89-2 Pyndine, 3-(1-nitroso-2-pyrrolicliryl). (S) 16543-55-8 N-Nitrosopiperidine Pipendine, 1-nitroso 100-75-4 Nitrosopymoldine Pyrolidine, 830-55-2 N-Nitrososarcosine Glycine, N-methyl-N-nitroso 13256-22-9 5-Nero-o-toludine Benzenamine, 2-methy4-5-nitro- 00-65-8 Octamethypyrophosphoramide Diphosphoramide, octamethys 152-16-9 Comium tetroxide Ownlum code (OaO) 20616-12-0 Paraldehyde 1.3.5-Tricicane, 2,4,6-mmethyl 123-63-7 Parathion Phosphorothiole acid, D.D-dethyl O-(4-nitropheny) ester 54-36-2 Pentachiorobenzene Benzene, pentachioro- 606-93-5 Pentachtorodiberzo-p-dieens Pentachiorodibercolurans [Appendix VIII] APPENDIX VIII-HAZAROOUS CONSTITUENTS-Continued Chemica Common name Chemical absuats name absuacts N Pentachioroelhene Ethane. pentachioro 76-01-7 Pentachlorontrobenzene (PCNB) Benzene. 82-68-8 Phenol, pentachioro 87-86-5 Pentachiorophenol Phenacetin Acetamide. N-(4-ethoxyphenyl) 62-44-2 Pheno Same 106-95-2 Phanylenediamine Benzenediamine 25265-76-3 Mercury (acatato-O)pheny) 62-36-4 Phenymercury acetate Phenythsourea Thoures phenyl. 103-85-5 Phosgene Carbonic dichionds 75-44-5 Phosphine Same 7803-51-2 Phorate Phosphorodithic acid, O,O-diethyl ester 298-02-2 Phthaic and esters N.O.S Phthake anhydnoe 85-44-B 2-Picoline Pyndine. 2-methyl- 109-06-8 Polychionnated biphenyts N.O.S. Potassum cyanide Same 151-50-6 Potassium silver cyanide Argentate(1-). bes/cyano-C). potessium 506-61-6 Pronamide Benzamide. 3.5-dachloro-N-(1,1-dirmethyi-2-propynyl) 23950-58-5 1.3-Propane sultone 1.2-Oxathiclane, 2.2-dioxide 1120-71-4 n-Propylamme 1-Propanamine 107-10-8 Propergy alcohol 2-Propyn-l-ol 107-19-7 Propylens dichionde Propane 1,2-dichloro 76-87-5 1,2-Propylenimme Azmome 2-mathy- 75-55-8 Propythiourace 4(1H)-Pytimidinone 2.3-dmnydro-6-propyl-2-thoxo 51-52-5 Pyndine Same 110-86-1 Reserpinen Tohmban-16-carboxytic acid methyl ester 50-55-5 Resorcino 1.3-Benzenediol 108-46-3 Secchann and salts 1,2-Benzisotwazol-3(2Hi-ona. 1.1-dioxide and salts 81-07-2 Satrole 1.3-Senzodioxole, 5-(2-propenyl) 94-59-7 Selenium dioxide Selerwous acid 7783-00-8 Selenium and compounds N.O.S Selenium 7782-49-2 Selenium sultice Same 7445-34-6 Selenoures Same 630-10-4 Silver and compounds. N.O.S.' Sever 7440-22-4 Silver cyanide Same 506-64-9 Silvex (2.4.5-TP) Propencic acid, 2-(2.4,5-inichlorophenoxy) 93-72-1 Sodium cyanide Same 143-33-9 Streptozotocin D-Glucopyranose, 2-deoxy-2-(3-methyl-3-natrosoureido) 18883-66-4 Stronbum auffide Same 1314-96-1 Strychnine and salts Strychnidin-10-one and setts 57-24-9 TCDO Dibenzo[b.e] (1,4)dioxin, 2,3,7,8-tetrachioro 1746-01-6 1.2.4.5-Tetrechlorobenzene Benzens, 1,2,4,5-tetrachioro- 95-94-3 Tetrachiorodibenzo-p-dioxins Teerschlorodibenzoturans Tetrachiorosthane *N.O.S.¹ Ethene. tetrachioro-, N.O.S 25322-20-7 1.1.1.2-Teeechioroethane Ethane, 1,1,1,2-trachichioro- 630-20-6 1.1.2.2-Terschloroethane Elhane, 1,1,2,2-latrachioro- 79-34-5 Tetrachiorosthylene Ethene, tetrachioro 127-18-4 2.3.4.6-Tetrachiorophenol Phenol, 2.3.4,6-tetrachioro- 58-90-2 Tetraethyldithiopyrophosphate Thiodiphosphone acid. tetreathy ester 3689-24-5 Tetreethy lead Plumbane, terracthyl- 78-00-2 Tetreethyipyrophosphate Diphosphone acid. tetracthyl ester 107-49-3 Tetrantromethane Methane, 509-14-8 Thankum and compounds N.O.S.' Thairm 7440-26-0 Thalk crode Thattium 000 OXIDE 1314-32-5 Thathum (B) acetate Acetic acid. that san 563-68-8 Thailum (n) carbonate Carbonic acid, dithallium(1 +) san 6533-73-9 Theirum (1) chlonds Thathum chloride 7791-12-0 That (1) nitrate Nitric acid, thailium(1 salt 10102-45-1 Thankum selervis Thatkum actende 12039-52-0 Thankum (b) sultate Sultune acid. thaikm salt 10031-59-1 Thioacetamide Ethanethicamide 62-55-5 Thiolanox 2-Sutanone, 3,3-dmnethyt-1-(methythio)O-[(nethylamno)carboryl)co 39196-18-4 Thomethano Methanethic 74-93-1 Thiophenot Benzenethic 108-98-5 Thiceemicarbazide Hydrazineca/bothioa/mide 79-19-6 Thoures Same 62-56-6 Threm Thioperoxydicarbonic diamide, Tetramethy1- 137-26-8 Totuens Benzene, methyl- 108-86-3 Toluenediame Benzenediamine, er-methyl- 25376-45-8 2.4-Tolueneckenena 1.3-Benzenediamine, 4-methyl- 95-80-7 2.6-Toluenediamme 1.3-Benzeneciamine. 2-methy 823-40-5 3,4-Toluenechamme 4-methyl- 496-72-0 Toluene disocyanate Benzens, 2.4-dmsocyanato-1-methyl- 584-84-9 p-Tolukine Benzenamine, 4-methys 106-49-0 c-Toluidine hydrochionde Benzenamine, 2-mathy4. hydrochioride 636-21-5 Toxaphene Same 8001-35-2 1,2.4-Tnichlorobenzene Senzene, 1.2.4-trichioro 120-82-1 1.1.2-Tnchioroethane Ethene, 1,1,2-trichioro 79-00-5 Trichtoroethylene Ethene. trichioro 79-01-6 Trichioromathanathiol Methanethiol. inchioro- 75-70-7 Trichioromonofuoromethane Methane, trichiorofluere- 75-69-4 2.4.5-Tnchlorophenol Phenol, 2,4,5-trichioro- 95-95-4 2.4.6-Trichicrophenol Phenol, 2.4.6-trichioro- 88-06-2 2,4,5-T Apelic acid. (2,4,5-trichlorophenoky) 03-76-5 Tnchioropropene N.O.S 1.2.3-Trichioropropane Propane, 1.2.3-trichioro- 96-18-4 O,O.O-Tnethylphosphorothioats Phosphorothic acid. O.O.O-triethyl enter 126-68-1 sym-Trinitrobenzens Benzene, 1.3.5-trinitro 99-35-4 auffide Azindine, 1,1',1'-phoaphanothioyidynwtris 52-24-4 Tes12.3-dibromopropyl)phospruate 1-Propenol 2. 3-dibrome-, phosphote (3:1) 126-72-7 APPENDIX VIII.-HAZARDOUS CONSTITUENTS-Continued Chemical Common name Chemical abstracts name abstracts No Trypan blue 2.7-Naphmelendisultonc acid. 3. 3.1(3) tetrasodium sah 72-57-1 Uracil mustard 2.4(1H.3H)-Pynmadinedione. 5-{bxs(2-chionoethyl)amno) 66-75-1 Same as CAS name Undecamethyienedamine N,N -bis(2-chiorobenzyl). dihydrochloride 2056-25-9 Vanadrum Vanadium oxide V.O. 1314-62-1 Vary chionge Ethene. chioro- 75-01-4 Wartann 2 H-1-Benzopyran-2-one. 4-hydroxy-3(3-oxo-1-phenylgutyl) 81-81-2 Zinc cyanide Same 557-21-1 Zinc phosphos Zinc phosphide P.Zn. 1314-84-7 3 The abbrevistion N.O.S. (not otherwise specified) signatures those members of the general class not specifically listed by name in the appendex ANEJO C-4 Appendix IX Wastes Excluded Under Sections 260.20 and 260.22 Appendix IX-Wastes Excluded Under incinerator at the Den- Metropolitan Cincinnati. Stuiced bottom asr may Farm Site in Sewer OH studge approximate McDowel Missouri. District of ty 25.000 CUDE after July 25 1985 so Greater yards). contained If long as (1) the inciner Cincinnati 260.20 and 260.22 the North Lagoon or ator 15 functioning prop- September 21. 1984 [Appendix IX added by 49 FR 37070. any. (2) a grab sample IS which contains EPA taken from each tank of Hazardous Waster September 21. 1984] wastewater generated Nos F001. F002 and the EP teachate val- F003 F004 and ues 00 not exceed 0.03 F005 TABLE 1.-WASTES EXCLUDED FROM NONppm for mercury. 0.14 Monroe Auto pom for selenium. and Paragouid Wastewater treatment SPECIFIC SOURCES 0.68 ppm for commun Equip- AR. sludge (EPA Hazardous ment Weste No F005 and (31 a gran sample IS taken from each drum of generated from electro plating operations son or ash generated after vacuum filtration Facility Address and a core sample IS CO. Waste description after November 27 1985 lected from each CHEAF The exclusion Does not Arco Chemical Miami, FL Dewatered wastewate TOM generated and the treatment studge (EPA EP teachate values oi apply to the sludge Co contained If: the on-site Hazardous Waste No. daily composites do no: impounement FO19) generated from exceed 0.044 ppm m ash the chemical converor CHEAF media for Siege St. Louis. Wastewater treatment Robert. Inc MO (EPA Hezardous Waste sion coating of skumierucy or 0.22 ppm in sh or CHEAF media for No F006) generated from num after April 29. 1986. elenium electroplating operations after November 27. 1985 Chamber- Hot Springs. Dewatered wastewater Falconer alcoher stewater treatment han- AR learment sludges Glass NY studges from the Texas ins... Dellas, TX Wastewater treatment Feather- EPA Hazardous Indust.. filter press and ments studges (EPA Hazerd line. Inc. Inc ous Waste Nos F006 Vaste No. F019 magnetic drum sepa. generated from the rator (EPA Hazaroand F019, generated after August 27. 1985. hemical conversion ous Waste No. F006) oating of aluminum generated from elec. from their electroplating after July 16. 1986. ng operations operations that have after July 16. 1986 been batch tested for Capitol Dewatered wastewater cadmium using the EP Gould Inc. W his treatment sludges (EPA eslewater treatment studge Products toxicity procedure and Harrisburg. will 3H (EPA Hazaroous Waste No Corp PA Hazardous Waste No. have been found 10 F006) gener ared from elac F019) generated from the contain less than 0.30 woplating operations aller chemical conversion cost- November 27. 1985 ppm cadmium in the E° ing of aluminum after extract. Washewater September 12. 1986 Imperial Clean Salid resin cakes contreatment studges tha: Salem IN exceed this level will be Cincinnati Cincinnati, Stuiced bottom sah taining EPA Hazardous considered a nazard- Metro- OH sludge (approximately Waste No. F002 generous waste. politan 25.000 cubic yards) ated after August 27. contained in the South 1985. from solvent re- United flerson- Dewatered wastewater Sewer Discovery operations. Technologies ville. IN treatment sludge (EPA trict Lagoon on September Automotive, Hezardous Waste No. 13. 1985 which con- Kay-Fries, Stoney Biological aeration to- Inc. FO19) generated from tains FPA nazardous Inc. Point, goon sludge and fil. the chemical conversion Waste Nos. F001. NY. tor press sludge genof aluminum after April F002, F003. F004, and erated after 29 1965 F005 September 21. 1964. Vermont Newark OH Wastewater treatment ortinenta Olympia which contain EPA lewatered wastewater treat. American. studge (EPA Hazaroous Can Co WA. Hazardous Waste ment sludges (EPA Hazard- Corp Waste No. F006. Nos F003 and F005 ous Waste No. F019) gengenerated from electro as well as that diserated from the chemical plating operations after conversion coating of alumiposed of in a holding November 27. 1985 num after September 12. lagoon as of September 12. 1984. Waterioo Pocahontas, Wastewater treatment 1986. Keymark Fonda. NY Dover Corp., Tuisa, OK Wastewater treatment Industries AR. sludges (EPA Haz- Dewatered wastewater Noms Div. Corp. sludge (EPA Hazardous ardous Waste No. treatment sludge (EPA Hazardous Waste No. Waste No. F019) F006) generated from FO06) generated from generated from chemical electropiating operconversion coating of ations after dewater. their electroplating opaluminum after ing and held on-site erations after April 29. November 27. 1985 on July 17. 1986 and 1988 any such studge gen- Loxcreen Hayti. MO Dewatered wastewater EPA's Mobile Denney Farm erated (after dews- Process wastewater. Company. treatment studges incineration Site: tering) after July 17. otary kim ash, CHEAF Inc. (EPA Hazardous System 1986 McDowell media, and other solids Waste No. F019) MO. texcept spent activated Watervillet. Waterviet, Wastewater treatment generated from the carbon) (EPA Hazard Areenal NY Bludges (EPA Hazardchemical conversion ous Waste Nos. F020. ous Waste No FO06) coating of aluminum F022. F023. F026. F027. generated from electroafter July 16. 1986. and F028) generated plating operations after during the field demon- (insert date of stration of EPA's Mobile publication). [Appendix IX) [Table i amended by 50 FR 30274. July 25. 1985: 20 FR 34692. August 27. 1985: 50 FR 37370. September 13. 1985; 50 FR 48910. November 27. 1985; 51 FR 1254. January 10. 1986: 51 FR 15889. April 29. 1986: 51 FR 25701. July 16. 1986: 51 FR 25891. July 1-. 1986: corrected by 51 FR 27038. July 29. 1986: amended by 51 FR 32460. September 12. 1986] TABLE 2-WASTES EXCLUDED FROM SPECIFIC SOURCES Facility Address Waste asscription (a) Wastes excluded from Amoco Oil Wood River. non-specific sources Company IL 150 million gallons of DAF float from petroleam refining contained in tour surge ponds after treatment with the Chemfix stabilization process This exclusion applies to the 150 mitlion galions of waste after chemical stabilizetion as long as the mixing ratios of the resgent with the waste are monitored continuously and do not vary outside of the limits presented in the demonstration samples. one grab sample is taken each hour from each treatmem unit. composited, and EP toxicity tests performed on each sample. It the levels of lead or total chromium exceed 0.5 ppm in the EP extract. then the waste that was processed during the compositing period is considered hazaroous: the treatment residue shall be pumped INTO bermed cells to ensure that the waste is identifiable in the event that removal is necessary. LPC Chem- Orrington. ME Brine purification muds cal and wastewater treatment studges generated after August 27. 1985 from their chloratkati manufacturing operations (EPA Hazardous Waste Nos K071 and K106) that have been batch tested for mercury using the EPA toxicity procedures and have been found to contain less than 0.05 ppm mercury in the EP extract. Brane purification mude and wastewater treatment skidges that exceed this level will be considered a hazardous waste. Mear) Peekskill. NY. Wastewater treatment Corp sludge (EPA Hazardous Waste Nos. K006 and K007) generated from the production of chrome Oxide green and iron blue pigments after November 27. 1985 TABLE 2 WASTES E *CLUDED FROM SPECIFIC Sounce $ -Contd. Facility Address Waste description Stauffer Erine purification muds Chemical Co Axis. AL generated from their chlorginal manufacturing operations (EPA Hazardous Waste No. K074) and disposed of in brine mud pond HWTF: 5 EP-201 Stauffer Chemical a St. Gabrie: LA Bnne purification muds. which have Deer washec and vaccum filtered generated atter August 27 1985 from their chior alka manufacturing operations (EPA Hazardous Waste No. K071) that have been batch tested for mercury using the EP toxicity procedure and have been found to contain less than 0.05 ppm in mercury in the EP extract Brine punfication muds that exceed this level will be consioered a hazerdous waste [Table 2 added by 50 FR 34692, August 27. 1985: amended by 50 FR 37370. September 13. 1985: 50 FR 48910. November 27. 1985: corrected by 51 FR 27038. July 29. 1986] TABLE 3-WASTES EXCLUDED FROM COMMER- CIAL CHEMICAL PRODUCTS. OFF-SPECIFICA- TION SPECIES CONTAINER RESIDUES. AND SOIL RESIDUES THEREOF Facility - Address Waste description Linion Carbide Tall LA Contaminated soil (spproxie- Corp. mately 11,000 cubic yards). which contains scroien in concentrations of less than 9 ppm ANEJO C-5 Appendix X Methods of Analysis for Chlorinated Dibenzo-p-Dioxins and Dibenzofurans 1234 Method 8280 [Appendix X added by 50 FR 1999, January 14, 1985) 1. Scope and Application 1.1. This method measures the concentration of chlorinated dibenzo-p-dioxins and chlorinated dibenzofurans in chemical wastes including still bottoms. filter aids. sludges. spent carbon, and reactor residues and in soils. 1.2 The sensitivity of this method is dependent upon the level of interferences. 1.3 This method is recommended for use only by analysts experienced with residue analysis and skilled in mass spectral analytical techniques 14 Because of the extreme toxicity of these compounds. the analyst must take necessary precautions to prevent exposure 10 himself. or to oth. ers. of materials known or believed to contain CDDs or CDFs. 2. Summary of the Method 2.1 This method is an analytical extraction cleanup procedure. and capillary column gas chromatograph-low resolution mass spectrometry method. using capilarry column GC/MS conditions and internal standard techniques, which allow for the measurement of PCDDs and PCDF's in the extract. 2.2 If interierences are encountered. the method provides selected general purpose cleanup procedures to aid the analyst in their elimination. 3. Interferences 3.1 Solvents reagents. glassware, and other sample processing hardware may yield discrete artifacts and/or elevated baselines causing misinterpretation of gas chromatograms. All of these materials must be demonstrated to be free from interferences under the conditions of the analysis by running method blanks. Specifto selection of reagents and purification of so)- vents by distillation in ali-glass systems may be required. 3.2 Interferences co-extracted from the samples will vary considerably from source to source. depending upon the diversity of the industry being sampled. PCDD is often associated with other interfering chlorinated compounds such as PCB's which may be at concentrations several orders of magnitude higher than that of PCDD. While general cleanup techniques are provided as part of this method. unique samples may require additional cleanup approaches to achieve the sensitivity stated in Table 1. 3.3 The other isomers of tetrachlorodibenzo- p-dioxin may interfere with the measurement of 2.3.7.8-TCDD. Capillary column gas chromatography is required to resolve those isomers that yield virtually identical mass fragmentstion patterns. 4. Apporatus and Materiols 4.1 Sampling equipment for discrete or composite sampling 4.1.1. Grab sample bottle- amber glass. 1-liter or 1-quart volume. French or Boston Round design is recommended. The container must be washed and solvent rinsed before use to minimize interferences 4.1.2. Bottle caps - threaded to screw on to the sample bottles. Caps must be lined with Teflon. Solvent washed foil used with the shiny side towards the sample. may be substituted for the Teflon if sample is not corrosive. 4.1.3. Composting equipment automatic or manual composing system. No tygon or rubber tubing may be used. and the system must incorporate glass sample containers for the collection of a minimum of 250 ml. Sample containers must be kept refrigerated after sampling. This method is appropriate for the analysis of letrapents. and bexachlorinated dibenzo-p-dioxins and dibenzofurans Analytical protocol for determination of TCDDs in phenolic chemical wastes and sot) samples obtained from the proxtmity of chemical dumps. TO Tiernan and M. Taylor. Brehm Laboratory Wright State University. Dayton. OH 45435. 'Analytical protocol for determination of chlorinated dibenzo-p-dioxins and chlorinated dibenzofurens in river water. T.O. Tiernan and M. Taylor. Brehm Laboratory. Wright State University. Dayton. OH 45435 In general. the techniques that should be used to handie these materials are those which are followed for redioactive or infectious laboratory materials. Amistance in evaluating laboratory practices may be obtained from industrial hygienists and persons specializing in safe laboratory practices. Typical infectious waste incinerstors are probably not astisfactory devices for disposal of materials highly contaminated with CDDs or CDFs. Safety instructions are outlined in EPA Test Method 613(4.0) See also: 1) "Program for monitoring potential contamination in the laboratory following the handling and analy. see of chlorinated dibenso-p-dioxins and dibanzofurans" by F.D. Hileman of al. In Human and Environmental Risks of Chlorinated Dioxine and Related Compounds Appendix X-Method of Analysis for Chlorinated dibenzo-p-dioxins and dibenzofurans 1.2.8.4 DR " R.E. Tucker. at al., eds., Plenum Publishing Corp. 1983. 2) Bafety procedures outlined in EPA Method 613. Federal Register volume 44. No 233. December a. 1979 4.2 Water bath heated. with contentric nag cover. capable of temperature control 2°C; The bath should be used in a hood 4.3 Gas chromatograph/mass spectrometer date system 4.3.1 Gas chromatograph An analytical system with a temperature-programmable gas chromatograph and all required accessories including syringes. analytical columns. and gases 4.3.2 Column: SP-2250 coated on a 30 m long X 0.25 mm I.D. glass column (Supeico No. 2. 3714 or equivalent). Glass capiliary column conditions: Helium carrier gas at 30 cm/sec linear velocity run sphtless Column temperature is 210°C 4.3.3 Mass spectrometer Capable of scanning from 35 to 450 amu every ) sec or less. utilizing 70 volts (nominal) electron energy in the electron impact ionization mode and producing B mass specirum which meets all the criteria in Table 2 when 50 ng of decafluorotriphenyl-phosphine (DFTPP) is injected through the GC inlet. The system must also be capable of selected ion monitoring (SIM) for at least 4 ions simultaneously. with a cycle time of 1 sec of less Minimum integration time for SIM is 100 ms. Selected ion monitoring is verified by injecting .015 ng of TCDD CI to give a minimum signal to noise ratio of 5 to 1 at mass 328. 4.3.4 GC/MS interface: Any GC-to-MS interface that gives acceptable calibration points at 50 ng per injection for each compound of interest and achieves acceptable tuning performance criteria (see Sections 6.1-6.3) may be used. GC-to-MS interfaces constructed of all glass or glass-lined materials are recommended. Glass can be deactivated by silanizing with dichlorodimethylsilane. The interface must be capable of transporting at least 10 ng of the components of interest from the GC to the MS 4.3.5 Data system: A computer system must be interfaced to the mass spectrometer. The system must allow the continuous acquisition and storage on machine-readable media of all mass spectra obtained throughout the duration of the chromatographic program. The computer must have software that can search any GC/MS data file for ions of a specific mass and that can plot such ion abundances versus time or scan number. This type of plot is defined as an Extracted lon Current Profile (EICP) Software must also be able to integrate the abundance. in any EICP. between specified time or scan number limits 4.4 Pipettes-Disposable. Pasteur. 150 mm long X 5 mm ID (Fisher Scientific Co. No. 13. 678-6A or equivalent). 4.5 Flint glass bottle (Teflon-lined screw cap). 4.6 Reacti-vial (silanized) (Pierce Chemical Co.) 5. Reagents 5.1 Potassium hydroixide-(ACS). 2% in distilled water 5.2 Sulfuric acid-(ACS). concentrated. 5.3 Methylene chloride. hexane. benzene. petroleum ether. methanol. tetradecane-pesticide quality or equivalent. 5.4 Prepare stock standard solutions of TCDD and 'CI-TCDD (molecular weight 328) in a glovebox. The stock solutions are stored in a glovebox. and checked frequently for signs of degradation or evaporation. especially just prior to the preparation of working standards. 5.5 Alumana-basic Woelm 80'200 mest. Before use activate overnight at 600°C. cool 10 room temperature in a dessicator 5.6 Prepurified nitrogen gas 6.0 Calibration 6.1 Before using any cleanup procedure. the analyst must process a series of calibration standards through the procedure to validate elution patterns and the absence of interierences from reagents 6.2 Prepare GC/MS calibration standards for the internal standard technique that will allow for measurement of relative response factors of at least three CDD/ CDD ratios Thus. for TCDDs. at least three TCDD "CI-TCDD and TCDF CL-TCDF must be determined. The ," CI-TCDD/F concentration in the standard should be fixed and selected to vield a reproducible response at the most sensitive setting of the mass spectrometer. Response factors for PCDD and HxCDD may be determined by measuring the response of the tetrachiorolabelied compounds relative to that of the un. labelled 1.2.3.4- er 2.3.7.8. TCDD 1.2.3.4.7- PCDD or 1.2.3.4.7.8-HxCDD. which are commercially available 6.3 Assemble the necessary GC/MS apparatus and establish operating parameters equivalent to those indicated in Section 11.1 of this method. Calibrate the GC/MS system accord. ing to Eichelberger et al. (1975) by the use of decafluorotripheny)-phosphine (DFTPP). By in. jecting calibration standards. establish the response factors for CDDs VS. CI-TCDD. and for CDFs VS. CI-TCDF. The detection limit provided in Table 1 should be verified by inie, ting .015 ng of CI-TCDD which should give a minimum signal to noise ratio of 5 to 1 at mass 328. 7. Quality Control 7.1 Before processing any samples. the analyst should demonstrate through the analysis of a distilled water method blank. that all glassware and reagents are interference-free. Each time a set of samples is extracted. or there is a change in reagents. a method blank should be processed as a safeguard against laboratory contamination 72 Standard quality assurance practices must be used with this method. Field replicates must be collected to measure the precision of the sampling technique Laboratory replicates must be analyzed to establish the precision of the analysis. Fortified samples must be analyzed to establish the accurecy of the analysis. 8 Sample Collection. Preservation. and Handling 6.1 Grab and composite samples must be collected in glass containers Conventional sampling practices should be followed. except that the bottle must not be prewashed with sample before collection. Composite samples should be collected in glass containers in accordance with the requirements of the RCRA program. Sampling equipment must be free of tygon and other potential sources of contamination "Ci-labelledi 2.3.7.8-TCDD and 23.7.6-TCDF are avail. able from K.O.R. Isotopes, and Cambridge Leotopes. Inc., Cambridge. MA. Proper standardization requires the use of a specific labelled isomer for each congener to be deter. mined. However the only labelled isoniers readily avail. able are "CH2.3.7.8-TCDD and "CI-2,3,7.8-TCDF This method therefore uses these isomers as surropates for the CDDs and CDFs. When other labelled CDDs and CDF: are available. their Due will be required 8:: The samples must be ICEC or refrigerated from the title of collection until extraction Chemical preservatives should not be used in the field unless more than 24 hours will elapse before delivery to the laboratory If an aqueous sample is taken and the sample will not be extracted within 48 hours of collection. the sample should be adjusted to a pH range of 6.0-8.0 with sodium hydroxide or sulfuric acid 8.3 All samples must be extracted within days and completely analyzed within 30 days of collection 9. Extraction and Cleanup Procedures 9.1 Use an aliquot of 1-10 8 sample of the chemical waste or soil to be analyzed Soils should be dried using a stream of prepurified nitrogen and pulverized in a ball-mill or similar device. Perform this operation in a clear area with proper hood space. Transfer the sample to a tared 125 ml flint glass bottle I'Teflon-lined screw cap) and determine the weight of the sample. Add an appropriate quantity of Cl-labelled 2.3.7.8-TCDD (adjust the quantity according to the required minimum detectable concentration). which is employed as an internal standard. 9.2 Extraction 9.2.1 Extract chemical waste samples by add. ing 10 m) methanol. 40 ml petroleum ether. 50 ml doubly distilled water. and then shaking the mixture for 2 minutes Tars should be completely dissolved in any of the recommended neat solvents. Activated carbon samples mus: be extracted with benzene using method 3540 in SW-846 (Test Methods for Evaluating Solid Waste-Physical/Chemical Methods. available from G.P.O. Stock #055-022-81001-2). Quantitatively transfer the organic extract or dissolved sample to a clean 250 ml flint glass bottle [Teflon lined screw cap). add 50 ml doubly distilled water and shake for 2 minutes. Discard the aqueous layer and proceed with Step 9.3 9.2.2 Extract soil samples by adding 40 ml of petroleum ether to the sample. and then shaking for 20 minutes. Quantitatively transfer the organic extract to a clean 250 ml flint glass bot. tie (Teflon-lined screw cap), add 50 ml doubly distilled water and shake for 2 minutes Discard the aqueous layer and proceed with Step 9.3. 93 Wash the organic layer with 50 ml of 20% aqueous polassium hydroxide by shaking for 10 minutes and then remove and discard the aqueons las er. 9.4 Wash the organic layer with 50 ml of doubly distilled water by shaking for 2 minutes. and discard the aqueous layer. 9.5 Cautiously add 50 ml concentrated sulfuric acid and shake for 10 minutes. Allow the mixture to stand until layers separate (spproximately 10 minutes). and remove and discard the acid layer. Repeat acid washing until no color is visible in the acid layer. 9.6 Add 50 ml of doubly distilled water to the organic extract and shake for 2 minutes. Remove and discard the aqueous layer and dry the organic layer by adding 10g of anhydrous sodium sulfate 9.7 Concentrate the extract to incipient dryness by heating in a 55' c water bath and similtaneously flowing a stream of prepurified nitrogen over the extract. Quantitatively transfer the residue to an alumina microcolumn fabricated as follows: 9.7.1 Cv: off the top section of a 10 ml disposable Pyrex pipette at the 4.0 ml mark and insert a plug of silanized glass wool into the tip of the lower portion of the pipette. 9.7.2 Add 2.8g of Woelm basic alumina (previously activated al 600 C overnight and then cooled to room temperature in a desiccator just prior to use). 9.7.3 Transfer sample extract with a small volume of methylene chloride. 0.8 Elute the microcolumn with 10 ml of 3% mothylene cholride-in-hexane followed by 15 ml of 20% methylene chloride-in-hexane and discard these efficents. Elute the column with 15 ml of 50% methylene chloride-inhexane and concentrate this effluent (55 C water bath. stream of prepurified nitrogen) to about 0.3-0.5 ml. 9.9 Quantitatively transfer the residue (using methylene chioride to rinse the container) 10 a silanized Reacti-Vial (Pierce Chemical Co.). Evaporate. using B stream of prepurified nitrogen. almost to dryness. rinse the walls of the vessel with approximately 0.5 ml nicthylene chioride, evaporate just to dryness. and tightly cap the vial. Store the vial at 5' C until analysis. at which time the sample is reconstituted by the addition of tridecane. 9.10 Approximately 1 hour before GC-MS HRGC-LRMS) analysis. dilute the residue in the micro-reaction vessel with an appropriate quantity of tridecane. Gently swirl the tridecane on the lower portion of the vessel to ensure dissolution of the CDDs and CDFs. Analyze a sample by GC/EC to provide insight into the complexity of the problem and to determine the manner in which the mass speciromeler should be used. Inject An enpropriate aliquot of the sample into the GC-MS instrument. using B syringe. 9.11 If. upon preliminary GC-MS analysis. the sample appears to contain interfering substances which obscure the analy for CDDs and CDFs. high performance liquid chromatographic (HPLC) cleanup of the exuact 16 accomplished, prior to further CC- MS analysis. 10. HPLC Cleanup Procedure' 10.1 Place approximately 2 ml of bexane in a 50 ml flint glass sample bottle fitted with a Teflon-lined cap. 10.2 At the appropriate retention time. position sample bottle to collect the required fraction. 10.3 Add 2 ml of 5% (w/v) sodium carbonate to the sample fraction collected and shake for one minute 10.4 Quantitatively remove the hexane layer (top layer) and transfer to a microreaction vessel. 10.5 Concentrate the fraction to dryness and retain for further analysis. 11. GC/MS Analysis For cleaning see also method #8320 or #8330, SW-846. Test Methods for Evaluating Solid Waste, Physic all Chemical Methods (1982). 11.1 The following column conditions are recommended: Glass capillary column conditions: SP-2250 coated on a 30 m ionz x 0.25 ram I.D. glass column (Supeico No. 2- 3714. or equivalent) with heiium cerrier gas at 30 cm/sec linear velocity: run splitiess. Column temperature is 210 C. Under these conditions the retention time for TCDDs is about 9.5 minutes. Calibrate the system deily with. # minimum, three injections of standard mixtures. 11.2 Calculate response factors for standards relative to "CI-TCDD/F (see Section 12). 11.3 Analyze samples with selected ion monitoring of at least two ions from Table 3. Proof of the presence of CDD or CDF exists if the following conditions are met: 11.3.1 The retention time of the peak in the sample must match that in the standard. within the performance specifications of the analytical system. 11.3.2 The ratio of ions must agree within 10% with that of the standard. 11.3.3 The retention time of the peuk maximum for the ions of interest must exactly match that of the peak. 11.4 Quanfitate the CDD and CDF peaks from the response relative to the SICI- TCDD/F internal standards. Recovery of the internal standard should be greater than 50 percent. 11.5 If a response is obtained for the appropriate set of ions, but is outside the, expected ratio. a co-eluting impurity may be suspected. In this case. another set of ions characteristic of the CDD/CDF molecules should he analyzed. For TCDD a good choice of ions is m/e 257 and m/e 259. For TCDF a good choice of ions is m/e 241 and 243. These ions are useful in characterizing the molecular structure to TCDD or TCDF. For analysis of TCDD good analytical technique W ould require using all four ions. m/e 257 320. 322. and 328. to verify detection and signal to noise ratio of 5 to 1. Suspected impurities such as DDE, DDD. or PCB residues can be confirmed by checking,for their major fragments. These materials can be removed by the cleanup columns. Failure to meet criteria should be explained in the report. or the sample reanalyzed. 11.6 If broad background interference restricts the sensitivity of the GC/MS analysis. the analyst should employ cleanup procedures and reanalyze by GC/MS. See section 10.0. 11.7 In those circumstances where these procedures do not yield a definitive conclusion. the use of high resolution mass spectrometry is suggested. 12. Calculations 12.1 Determine the concentration of individual compounds according to the formula: A = internal standard added 10 inc sample gm of sample extracted A. = area of characteristic ion of the compound being quantified. A., = crea of characteristic ion of the internal standard where AXA, Concentration, µg/ gm R,=response factor Response factors are calculated using data obtained from the analysis of standards according to the formula: A,XC, Rf AnXC, where: concentration of the internal standard C, concentration of the standard compound 12.2 Report results in micrograms per gram without correction for recovery data. When duplicate and spiked samples are analyzed. all data obtained should be reported. 12.3 Accuracy and Precision. No date are wailable at this time. TABLE 1.-GAS CHROMATOGRAPHY OF TCDD Reten- Detec. Commn ton time tion format (min.) (Mg/kg) Glass capitary 9.5 0.003 1 Detection lemit for liquid samples # 0.003 Mg/L, This as calculated from me minumum detectable GC response being equal to five times the GC background noise assuming # ml effective final volume of the 1 No samoie extract and a GC mjection of 5 microfiers Detection levels apply to nom election capture and GC/MS detection For turner drais see 44 FR 69526 (December 3. 1979) TABLE 2.-DFTPP KEY IONS AND ION ABUNDANCE CRITERIA' Mass ton abundance critens 51 30-80% of mass 196 66 Less men 2% of mass 69 70 Less than 2% of mass 69 127 40-60% of mass 198 197 Less than 1% of mass 196 198 Base peat. 100% relative abundance 199 5-9% of mass 198 276 10-30% of mass 196. 365 Greater than 1% of mess 196 441 Present but less man mass 443 442 Grester than 40% of maes 196 443 17-23% of mass 442 W. Eicholberger, LE. Harris, and W.L Budde 1975 Reference compound to colorate ion abundance measure ment on gas chromatography-mass apactrometry. Anarytical Chemistry 47:995 The proper amount of standard to be used is determined from the calibration curve (See Section 6.0) 'If standards for PCDDs/Fs and HxCDDWFs are not available. response factors for ions derived from these congeners are calculated relative to PCI- TCDD/F. The analyst may use response factors for 1.234 or 2.27.B-TCDD. 1.2.3.4.7-PeCDD. or 1.23.4.7.8-HxCDD for quantitation of TCDDs/Fa. PeCDDs/Fa and HxCDDs/Fs. respectively. Implich in this requirement is the assumption that the same response is obtained from PCDDs/Fe econtaining the name numbers of chlorine atoms. TABLE 3.-LIST OF ACCURATE MASSES MONITORED USING GC SELECTED-ION MONITORING Low RESOLUTION. MASS SPECTROMETRY FOR SIMULTANEOUS DETERMINATION OF TETRA-, PENTA., AND HEXACHLORINATED DIBENZO-P-DIOXINS AND DIBENZOFURANS Approx- Number mate Montored m/z Monitored m/2 theoretical of chionne tor for ratio Class of chionnated dicenzodioxin or dibanzeturan doe a diberteturans expected substn. Fuants (x) C.H.,OC, on best of (SOLODIC abundance Tera 4 319897 $ 303,902 074 321.894 305.903 1.00 327.885 * 311.894 256.033 0.21 258.530 0.20 Pents 5 353.856 ' 387.863 0.57 $55.855 339.860