9VAC25-32-356. Pollutant monitoring and limits

Article 2 Operational and Monitoring Requirements A. Bulk biosolids or biosolids sold or given away in a bag or other container shall be monitored for the parameters identified in Table 1 of this section: TABLE 1 PARAMETERS for BIOSOLIDS ANALYSIS (1) TABLE 1 PARAMETERS for BIOSOLIDS ANALYSIS (1) Pollutant Pollutant Percent solids (%) Percent solids (%) Volatile solids (%) Volatile solids (%) pH (standard units) pH (standard units) Total Kjeldahl nitrogen (%) Total Kjeldahl nitrogen (%) Ammonia nitrogen (%) Ammonia nitrogen (%) Nitrates (mg/kg) Nitrates (mg/kg) Total phosphorus (%) Total phosphorus (%) Total potassium (%) Total potassium (%) Alkalinity as CaCO 3 (mg/kg) (2) Alkalinity as CaCO 3 (mg/kg) (2) Arsenic (mg/kg) Arsenic (mg/kg) Cadmium (mg/kg) Cadmium (mg/kg) Copper (mg/kg) Copper (mg/kg) Lead (mg/kg) Lead (mg/kg) Mercury (mg/kg) Mercury (mg/kg) Molybdenum (mg/kg) Molybdenum (mg/kg) Nickel (mg/kg) Nickel (mg/kg) Selenium (mg/kg) Selenium (mg/kg) Zinc (mg/kg) Zinc (mg/kg) (1) Values reported on a dry weight basis unless indicated. (2) Lime treated biosolids (10% or more lime by weight) shall be analyzed for percent CaCO 3 . (1) Values reported on a dry weight basis unless indicated. (2) Lime treated biosolids (10% or more lime by weight) shall be analyzed for percent CaCO 3 . B. Biosolids pollutant limits. 1. Bulk biosolids or biosolids sold or given away in a bag or other container shall not be applied to the land if the concentration of any pollutant in the biosolids exceeds the ceiling concentration for the pollutant in Table 2 of this section. 2. If bulk biosolids is applied to agricultural land, forest, a public contact site, or a reclamation site, either: a. The cumulative loading rate for each pollutant shall not exceed the cumulative pollutant loading rate for the pollutant in Table 3 of this section; or b. The concentration of each pollutant in the biosolids shall not exceed the concentration for the pollutant in Table 4 of this section. 3. If bulk biosolids is applied to a lawn or a home garden, the concentration of each pollutant in the biosolids shall not exceed the concentration for the pollutant in Table 4 of this section. 4. If biosolids is sold or given away in a bag or other container for application to the land, either: a. The concentration of each pollutant in the biosolids shall not exceed the concentration for the pollutant in Table 4 of this section; or b. The product of the concentration of each pollutant in the biosolids and the annual whole sludge application rate for the biosolids shall not cause the annual pollutant loading rate for the pollutant in Table 5 of this section to be exceeded. The procedure used to determine the annual whole sludge application rate is presented in subsection D of this section. C. Pollutant concentrations and loading rates - biosolids. TABLE 2 CEILING CONCENTRATIONS TABLE 2 CEILING CONCENTRATIONS Pollutant Ceiling Concentration (milligrams per kilogram)* Pollutant Ceiling Concentration (milligrams per kilogram)* Arsenic 75 Arsenic 75 Cadmium 85 Cadmium 85 Copper 4,300 Copper 4,300 Lead 840 Lead 840 Mercury 57 Mercury 57 Molybdenum 75 Molybdenum 75 Nickel 420 Nickel 420 Selenium 100 Selenium 100 Zinc 7,500 Zinc 7,500 *Dry weight basis *Dry weight basis TABLE 3 CUMULATIVE POLLUTANT LOADING RATES (1) TABLE 3 CUMULATIVE POLLUTANT LOADING RATES (1) Cumulative Pollutant Loading Rate Cumulative Pollutant Loading Rate Pollutant (kilograms per hectare) (pounds per acre) Pollutant (kilograms per hectare) (pounds per acre) Arsenic (2) 41 36 Arsenic (2) 41 36 Cadmium 39 35 Cadmium 39 35 Copper 1,500 1,340 Copper 1,500 1,340 Lead 300 270 Lead 300 270 Mercury 17 16 Mercury 17 16 Molybdenum (2) Molybdenum (2) Nickel 420 375 Nickel 420 375 Selenium 100 89 Selenium 100 89 Zinc 2,800 2,500 Zinc 2,800 2,500 Notes: (1) Such total applications to be made on soils with the biosolids/soil mixture pH adjusted to 6.0 or greater if the biosolids cadmium content is greater than or equal to 21 mg/kg. The maximum cumulative application rate is limited for all ranges of cation exchange capacity due to soil background pH in Virginia of less than 6.5 and lack of regulatory controls of soil pH adjustment after biosolids application ceases. (2) The maximum cumulative application is currently under study by USEPA. Research suggests that for Molybdenum a cumulative pollutant loading rate below 40 kg/hectare may be appropriate to reduce the risk of copper deficiency in grazing animals. Notes: (1) Such total applications to be made on soils with the biosolids/soil mixture pH adjusted to 6.0 or greater if the biosolids cadmium content is greater than or equal to 21 mg/kg. The maximum cumulative application rate is limited for all ranges of cation exchange capacity due to soil background pH in Virginia of less than 6.5 and lack of regulatory controls of soil pH adjustment after biosolids application ceases. (2) The maximum cumulative application is currently under study by USEPA. Research suggests that for Molybdenum a cumulative pollutant loading rate below 40 kg/hectare may be appropriate to reduce the risk of copper deficiency in grazing animals. TABLE 4 POLLUTANT CONCENTRATIONS TABLE 4 POLLUTANT CONCENTRATIONS Pollutant Monthly Average Concentration (milligrams per kilogram)* Pollutant Monthly Average Concentration (milligrams per kilogram)* Arsenic 41 Arsenic 41 Cadmium 39 Cadmium 39 Copper 1,500 Copper 1,500 Lead 300 Lead 300 Mercury 17 Mercury 17 Molybdenum (1) Molybdenum (1) Nickel 420 Nickel 420 Selenium 100 Selenium 100 Zinc 2,800 Zinc 2,800 *Dry weight basis Note: (1) The monthly average concentration is currently under study by USEPA. Research suggests that a monthly average Molybdenum concentration below 40 mg/kg may be appropriate to reduce the risk of copper deficiency in grazing animals. *Dry weight basis Note: (1) The monthly average concentration is currently under study by USEPA. Research suggests that a monthly average Molybdenum concentration below 40 mg/kg may be appropriate to reduce the risk of copper deficiency in grazing animals. TABLE 5 ANNUAL POLLUTANT LOADING RATES (1) TABLE 5 ANNUAL POLLUTANT LOADING RATES (1) Annual Pollutant Loading Rate (per 365-day period) Annual Pollutant Loading Rate (per 365-day period) Pollutant (kilograms per hectare) (pounds per acre) Pollutant (kilograms per hectare) (pounds per acre) Arsenic (2) 2.0 1.8 Arsenic (2) 2.0 1.8 Cadmium 1.9 1.7 Cadmium 1.9 1.7 Copper 75 67 Copper 75 67 Lead 15 13 Lead 15 13 Mercury 0.85 0.76 Mercury 0.85 0.76 Molybdenum (2) Molybdenum (2) Nickel 21 19 Nickel 21 19 Selenium 5.0 4.6 Selenium 5.0 4.6 Zinc 140 125 Zinc 140 125 Notes: (1) Such total applications to be made on soils with the biosolids/soil mixture pH adjusted to 6.0 or greater if the biosolids cadmium content is greater than or equal to 21 mg/kg. The maximum cumulative application rate is limited for all ranges of cation exchange capacity due to soil background pH in Virginia of less than 6.5 and lack of regulatory controls of soil pH adjustment after biosolids application ceases. (2) The maximum cumulative application is currently under study by USEPA. Notes: (1) Such total applications to be made on soils with the biosolids/soil mixture pH adjusted to 6.0 or greater if the biosolids cadmium content is greater than or equal to 21 mg/kg. The maximum cumulative application rate is limited for all ranges of cation exchange capacity due to soil background pH in Virginia of less than 6.5 and lack of regulatory controls of soil pH adjustment after biosolids application ceases. (2) The maximum cumulative application is currently under study by USEPA. D. Procedures to determine the annual whole sludge application rate (AWSAR) for biosolids. Subdivision B 4 b of this section requires that the product of the concentration for each pollutant listed in Table 4 of this section in biosolids sold or given away in a bag or other container for application to the land and the AWSAR for the biosolids not cause the annual pollutant loading rate for the pollutant in Table 5 to be exceeded. This subsection contains that procedure used to determine the AWSAR for a biosolids that does not cause the annual pollutant loading rates (APLR) in Table 5 of this section to be exceeded. 1. The relationship between the APLR for a pollutant and the AWSAR for a biosolids is shown in equation (1): EQUATION (1) EQUATION (1) APLR = C X AWSAR X 0.001 APLR = C X AWSAR X 0.001 APLR = Annual pollutant loading rate in kilograms per hectare per 365-day period APLR = Annual pollutant loading rate in kilograms per hectare per 365-day period C = Pollutant concentration in milligrams per kilogram of total solids (dry weight basis) C = Pollutant concentration in milligrams per kilogram of total solids (dry weight basis) AWSAR = Annual whole sludge application rate in metric tons per hectare per 365-day period (dry weight basis) AWSAR = Annual whole sludge application rate in metric tons per hectare per 365-day period (dry weight basis) 0.001 = A conversion factor 0.001 = A conversion factor 2. To determine the AWSAR, equation (1) is rearranged into equation (2): EQUATION (2) EQUATION (2) AWSAR = APLR/(C X 0.001) AWSAR = APLR/(C X 0.001) AWSAR = Annual whole sludge application rate in metric tons per hectare per 365-day period (dry weight basis) AWSAR = Annual whole sludge application rate in metric tons per hectare per 365-day period (dry weight basis) APLR = Annual pollutant loading rate in kilograms per hectare per 365-day period APLR = Annual pollutant loading rate in kilograms per hectare per 365-day period C = Pollutant concentration in milligrams per kilogram of total solids (dry weight basis) C = Pollutant concentration in milligrams per kilogram of total solids (dry weight basis) 0.001 = A conversion factor 0.001 = A conversion factor 3. The procedure used to determine the AWSAR for a biosolids is presented below: a. Analyze a sample of the biosolids to determine the concentration for each of the pollutants listed in Table 4 of this section in the biosolids. b. Using the pollutant concentrations from subdivision 3 a of this subsection and the APLRs from Table 5 of this section, calculate an AWSAR for each pollutant using Equation (2) above. c. The AWSAR for the biosolids is the lowest AWSAR calculated in subdivision 3 b of this subsection.