35 Ill. Adm. Code 721.933
Standards: Closed-Vent Systems and Control Devices
Section 721.933 Standards: Closed-Vent Systems and
Control Devices
a) Applicability
1) The
remanufacturer or other person that stores or treats the hazardous secondary
materials in hazardous secondary material management units using closed-vent
systems and control devices used to comply with provisions of this Part must
comply with the provisions of this Section.
2) This
subsection (a)(2) corresponds with 40 CFR 261.1033, which USEPA has marked
"reserved". This statement maintains structural consistency with the
federal regulations.
b) A
control device involving vapor recovery (e.g., a condenser or adsorber) must be
designed and operated to recover the organic vapors vented to it with an
efficiency of 95 weight percent or greater unless the total organic emission
limits of Section 721.932(a)(1) for all affected process vents can be attained
at an efficiency less than 95 weight percent.
c) An
enclosed combustion device (e.g., a vapor incinerator, boiler, or process
heater) must be designed and operated to reduce the organic emissions vented to
it by 95 weight percent or greater; to achieve a total organic compound
concentration of 20 ppmv, expressed as the sum of the actual compounds, not
carbon equivalents, on a dry basis corrected to three percent oxygen; or to
provide a minimum residence time of 0.50 seconds at a minimum temperature of
760°C. If a boiler or process heater is used as the control device, then the
vent stream must be introduced into the flame zone of the boiler or process
heater.
d) Flares
1) A
flare must be designed for and operated with no visible emissions, as
determined by the methods specified in subsection (e)(1), except for periods
not to exceed a total of five minutes during any two consecutive hours.
2) The owner
or operator must operate a flare with a flame present at all times, as
determined by the methods specified in subsection (f)(2)(C).
3) A
flare must be used only if the net heating value of the gas being combusted is
11.2 MJ/scm (300 Btu/scf) or greater if the flare is steam-assisted or
air-assisted; or if the net heating value of the gas being combusted is 7.45
MJ/scm (200 Btu/scf) or greater if the flare is non-assisted. The net heating
value of the gas being combusted must be determined by the methods specified in
subsection (e)(2).
4) Exit Velocity
A) A
steam-assisted or unassisted flare must be designed for and operated with an
exit velocity, as determined by the methods specified in subsection (e)(3),
less than 18.3 m/s (60 ft/s), except as provided in subsections (d)(4)(B) and
(C).
B) A
steam-assisted or non-assisted flare designed for and operated with an exit
velocity, as determined by the methods specified in subsection (e)(3), equal to
or greater than 18.3 m/s (60 ft/s) but less than 122 m/s (400 ft/s) is allowed
if the net heating value of the gas being combusted is greater than 37.3 MJ/scm
(1,000 Btu/scf).
C) A
steam-assisted or non-assisted flare designed for and operated with an exit
velocity, as determined by the methods specified in subsection (e)(3), less
than the velocity, V
max
, as determined by the method specified in
subsection (e)(4), and less than 122 m/s (400 ft/s) is allowed.
5) An
air-assisted flare must be designed and operated with an exit velocity less
than the velocity, V
max
, as determined by the method specified in
subsection (e)(5).
6) A
flare used to comply with this Section must be steam-assisted, air-assisted, or
unassisted.
e) Compliance Determination
and Equations
1) Reference
Method 22 (Visual Determination of Fugitive Emissions from Material Sources and
Smoke Emissions from Flares) in appendix A to 40 CFR 60 (Test Methods),
incorporated by reference in 35 Ill. Adm. Code 720.111, must be used to
determine the compliance of a flare with the visible emission provisions of
this Subpart AA. The observation period is two hours and must be used according
to Method 22.
2) The
net heating value of the gas being combusted in a flare must be calculated
using the following equation:
Where:
H
T
=
Net heating value of the sample,
MJ/scm; if the net enthalpy per mole of offgas is based on combustion at 25°C
and 760 mm Hg, but the standard temperature for determining the volume
corresponding to one mol is 20°C
K
=
Constant, 1.74 × 10
-7
(1/ppm) (g mol/scm)
(MJ/kcal) if standard temperature for (g mol/scm) is 20°C
C
i
=
Concentration of sample component i in ppm on a wet basis,
as measured for organics by Reference Method 18 (Measurement of Gaseous
Organic Compound Emissions by Gas Chromatography) in appendix A to 40 CFR 60
(Test Methods), incorporated by reference in 35 Ill. Adm. Code 720.111, and
measured for hydrogen and carbon monoxide by ASTM D 1946-90, incorporated by
reference in Section 720.111
H
i
=
Net heat of combustion of sample component i, kcal/g mol
at 25°C and 760 mm Hg. The heats of combustion may be determined using ASTM
D 2382-83, incorporated by reference in Section 720.111, if published values
are not available or cannot be calculated.
3) The
actual exit velocity of a flare must be determined by dividing the volumetric
flow rate (in units of standard temperature and pressure), as determined by
Reference Methods 2 (Determination of Stack Gas Velocity and Volumetric Flow
Rate (Type S Pitot Tube)), 2A (Direct Measurement of Gas Volume through Pipes
and Small Ducts), 2C (Determination of Gas Velocity and Volumetric Flow Rate in
Small Stacks or Ducts (Standard Pitot Tube)), or 2D (Measurement of Gas Volume
Flow Rates in Small Pipes and Ducts) in appendix A to 40 CFR 60 (Test Methods),
each incorporated by reference in 35 Ill. Adm. Code 720.111, as appropriate, by
the unobstructed (free) cross-sectional area of the flare tip.
4) The
maximum allowed velocity in m/s, V
max
, for a flare complying with
subsection (d)(4)(C) must be determined by the following equation:
Where:
H
T
=
The net heating value as
determined in subsection (c)(2)
5) The
maximum allowed velocity in m/s, V
max
, for an air-assisted flare
must be determined by the following equation:
Where:
H
T
=
The net heating value as
determined in subsection (c)(2)
f) The
remanufacturer or other person that stores or treats the hazardous secondary
material must monitor and inspect each control device required to comply with this
section to ensure proper operation and maintenance of the control device by
implementing the following requirements:
1) Install,
calibrate, maintain, and operate according to the manufacturer's specifications
a flow indicator that provides a record of vent stream flow from each affected
process vent to the control device at least once every hour. The flow
indicator sensor must be installed in the vent stream at the nearest feasible
point to the control device inlet but before the point at which the vent
streams are combined.
2) Install,
calibrate, maintain, and operate according to the manufacturer's specifications
a device to continuously monitor control device operation as specified below:
A) For a
thermal vapor incinerator, a temperature monitoring device equipped with a
continuous recorder. The device must have an accuracy of ±1 percent of the
temperature being monitored in °C or ±0.5°C, whichever is greater. The
temperature sensor must be installed at a location in the combustion chamber
downstream of the combustion zone.
B) For a
catalytic vapor incinerator, a temperature monitoring device equipped with a
continuous recorder. The device must be capable of monitoring temperature at
two locations and have an accuracy of ±1 percent of the temperature being
monitored in °C or ±0.5°C, whichever is greater. One temperature sensor must
be installed in the vent stream at the nearest feasible point to the catalyst
bed inlet and a second temperature sensor must be installed in the vent stream
at the nearest feasible point to the catalyst bed outlet.
C) For a
flare, a heat sensing monitoring device equipped with a continuous recorder
that indicates the continuous ignition of the pilot flame.
D) For a
boiler or process heater having a design heat input capacity less than 44 MW, a
temperature monitoring device equipped with a continuous recorder. The device
must have an accuracy of ±1 percent of the temperature being monitored in °C or
±0.5°C, whichever is greater. The temperature sensor must be installed at a
location in the furnace downstream of the combustion zone.
E) For a
boiler or process heater having a design heat input capacity greater than or
equal to 44 MW, a monitoring device equipped with a continuous recorder to
measure a parameter(s) that indicates good combustion operating practices are
being used.
F) For a condenser,
either:
i) A
monitoring device equipped with a continuous recorder to measure the
concentration level of the organic compounds in the exhaust vent stream from
the condenser; or
ii) A
temperature monitoring device equipped with a continuous recorder. The device
must be capable of monitoring temperature with an accuracy of ±1 percent of the
temperature being monitored in °C or ±0.5°C, whichever is greater. The temperature
sensor must be installed at a location in the exhaust vent stream from the
condenser exit (i.e., product side).
G) For a
carbon adsorption system that regenerates the carbon bed directly in the
control device like a fixed-bed carbon adsorber, either:
i) A
monitoring device equipped with a continuous recorder to measure the
concentration level of the organic compounds in the exhaust vent stream from
the carbon bed; or
ii) A
monitoring device equipped with a continuous recorder to measure a parameter
that indicates the carbon bed is regenerated on a regular, predetermined time
cycle.
3) Inspect
the readings from each monitoring device required by subsections (f)(1) and
(f)(2) at least once each operating day to check control device operation and,
if necessary, immediately implement the corrective measures necessary to ensure
the control device operates in compliance with this Section.
g) A
remanufacturer or other person that stores or treats hazardous secondary
material in a hazardous secondary material management unit using a carbon
adsorption system like a fixed-bed carbon adsorber that regenerates the carbon
bed directly onsite in the control device must replace the existing carbon in
the control device with fresh carbon at a regular, predetermined time interval
that is no longer than the carbon service life established as a requirement of
Section 721.935(b)(4)(C)(vi).
h) A
remanufacturer or other person that stores or treats hazardous secondary
material in a hazardous secondary material management unit using a carbon
adsorption system like a carbon canister that does not regenerate the carbon
bed directly onsite in the control device must replace the existing carbon in
the control device with fresh carbon on a regular basis by using one of the following
procedures:
1) Monitor
the concentration level of the organic compounds in the exhaust vent stream
from the carbon adsorption system on a regular schedule and replace the
existing carbon with fresh carbon immediately when carbon breakthrough is indicated.
The monitoring frequency must be daily or at an interval no greater than 20
percent of the time required to consume the total carbon working capacity
established as a requirement of Section 721.935(b)(4)(C)(vii), whichever is
longer.
2) Replace
the existing carbon with fresh carbon at a regular, predetermined time interval
that is less than the design carbon replacement interval established as a
requirement of Section 721.935(b)(4)(C)(vii).
i) An
alternative operational or process parameter may be monitored if it can be
demonstrated that another parameter will ensure that the control device is
operated in conformance with these standards and the control device's design
specifications.
j) A
remanufacturer or other person that stores or treats hazardous secondary
material at an affected facility seeking to comply with the provisions of this
part by using a control device other than a thermal vapor incinerator,
catalytic vapor incinerator, flare, boiler, process heater, condenser, or carbon
adsorption system must develop documentation including sufficient information
to describe the control device operation and identify the process parameter or
parameters that indicate proper operation and maintenance of the control
device.
k) A closed-vent system
must meet either of the following design requirements:
1) A
closed-vent system must be designed to operate with no detectable emissions, as
indicated by an instrument reading of less than 500 ppmv above background as
determined by the procedure in Section 721.934(b), and by visual inspections;
or
2) A
closed-vent system must be designed to operate at a pressure below atmospheric
pressure. The system must be equipped with at least one pressure gauge or
other pressure measurement device that can be read from a readily accessible
location to verify that negative pressure is being maintained in the
closed-vent system when the control device is operating.
l) The
remanufacturer or other person that stores or treats the hazardous secondary
material must monitor and inspect each closed-vent system required to comply
with this section to ensure proper operation and maintenance of the closed-vent
system by implementing the following requirements:
1) Each
closed-vent system that is used to comply with subsection (k)(1) must be
inspected and monitored in compliance with the following requirements:
A) An
initial leak detection monitoring of the closed-vent system must be conducted
by the remanufacturer or other person that stores or treats the hazardous secondary
material on or before the date that the system becomes subject to this section.
The remanufacturer or other person that stores or treats the hazardous
secondary material must monitor the closed-vent system components and
connections using the procedures specified in Section 721.934(b) to demonstrate
that the closed-vent system operates with no detectable emissions, as indicated
by an instrument reading of less than 500 ppmv above background.
B) After
initial leak detection monitoring required in subsection (l)(1)(A), the
remanufacturer or other person that stores or treats the hazardous secondary
material must inspect and monitor the closed-vent system as follows:
i) Closed-vent
system joints, seams, or other connections that are permanently or semi-permanently
sealed (e.g., a welded joint between two sections of hard piping or a bolted
and gasketed ducting flange) must be visually inspected at least once per year
to check for defects that could result in air pollutant emissions. The
remanufacturer or other person that stores or treats the hazardous secondary
material must monitor a component or connection using the procedures specified
in Section 721.934(b) to demonstrate that it operates with no detectable
emissions following any time the component is repaired or replaced (e.g., a
section of damaged hard piping is replaced with new hard piping) or the
connection is unsealed (e.g., a flange is unbolted).
ii) Closed-vent
system components or connections other than those specified in subsection (l)(1)(B)(i)
must be monitored annually and at other times as requested by the Agency,
except as provided for in subsection (o), using the procedures specified in
Section 721.934(b) to demonstrate that the components or connections operate
with no detectable emissions. The Agency must make any request for monitoring
in writing to the remanufacturer or other person that stores or treats the
hazardous secondary material.
C) If a
defect or leak is detected, the remanufacturer or other person that stores or
treats the hazardous secondary material must repair the defect or leak in compliance
with subsection (l)(3).
D) The
remanufacturer or other person that stores or treats the hazardous secondary
material must maintain a record of the inspection and monitoring in compliance
with the requirements specified in Section 721.935.
2) Each
closed-vent system that is used to comply with subsection (k)(2) must be
inspected and monitored as follows:
A) The
closed-vent system must be visually inspected by the remanufacturer or other
person that stores or treats the hazardous secondary material to check for
defects that could result in air pollutant emissions. Defects include visible
cracks, holes, or gaps in ductwork or piping or loose connections.
B) The
remanufacturer or other person that stores or treats the hazardous secondary
material must perform an initial inspection of the closed-vent system on or
before the date that the system becomes subject to this Section. Thereafter,
the remanufacturer or other person that stores or treats the hazardous
secondary material must perform the inspections at least once every year.
C) If a
defect or leak is detected, the remanufacturer or other person that stores or
treats the hazardous secondary material must repair the defect or the leak in compliance
with subsection (l)(3).
D) The
remanufacturer or other person that stores or treats the hazardous secondary
material must maintain a record of the inspection and monitoring in compliance
with the requirements specified in Section 721.935.
3) The
remanufacturer or other person that stores or treats the hazardous secondary
material must repair all detected defects as follows:
A) Detectable
emissions, as indicated by visual inspection, or by an instrument reading
greater than 500 ppmv above background, must be controlled as soon as
practicable, but not later than 15 calendar days after the emission is
detected, except as provided for in subsection (l)(3)(C).
B) A
first attempt at repair must be made within 5 calendar days after the emission
is detected.
C) Delay
of repair of a closed-vent system for which leaks have been detected is allowed
if the repair is technically infeasible without a process unit shutdown, or if
the remanufacturer or other person that stores or treats the hazardous
secondary material determines that emissions resulting from immediate repair
would be greater than the fugitive emissions likely to result from delay of
repair. Repair of the equipment must be completed by the end of the next
process unit shutdown.
D) The
remanufacturer or other person that stores or treats the hazardous secondary
material must maintain a record of the defect repair in compliance with the
requirements specified in Section 721.935.
m) Closed-vent
systems and control devices used to comply with provisions of this Subpart AA
must be operated at all times when emissions may be vented to them.
n) The
owner or operator using a carbon adsorption system to control air pollutant
emissions must document that all carbon that is a hazardous waste and that is
removed from the control device is managed in one of the following manners,
regardless of the average volatile organic concentration of the carbon:
1) Regenerated
or reactivated in a thermal treatment unit that meets one of the following:
A) The
owner or operator of the unit has been issued a final permit under 35 Ill. Adm.
Code 702, 703, and 705 that implements Subpart X; or
B) The
unit is equipped with and operating air emission controls in compliance with
the applicable requirements of Subparts AA and CC or Subparts AA and CC of 35
Ill. Adm. Code 725; or
C) The
unit is equipped with and operating air emission controls in compliance with a
national emission standard for hazardous air pollutants under 40 CFR 61
(National Emission Standards for Hazardous Air Pollutants) or 40 CFR 63
(National Emission Standards for Hazardous Air Pollutants for Source
Categories), each incorporated by reference in 35 Ill. Adm. Code 720.111(b).
2) Incinerated
in a hazardous waste incinerator for which the owner or operator either:
A) Has
been issued a final permit under 35 Ill. Adm. Code 702, 703, and 705 that
implements Subpart O; or
B) Has
designed and operates the incinerator in compliance with the interim status
requirements of Subpart O of 35 Ill. Adm. Code 725.
3) Burned
in a boiler or industrial furnace for which the owner or operator either:
A) Has
been issued a final permit under 35 Ill. Adm. Code 702, 703, and 705 that
implements Subpart H of 35 Ill. Adm. Code 726; or
B) Has
designed and operates the boiler or industrial furnace in compliance with the
interim status requirements of Subpart H of 35 Ill. Adm. Code 726.
o) Any
components of a closed-vent system that are designated, as described in Section
721.935(c)(9), as unsafe to monitor are exempt from subsection (l)(1)(B)(ii) if
both of the following conditions are met:
1) The
remanufacturer or other person that stores or treats the hazardous secondary
material in a hazardous secondary material management unit using a closed-vent
system determines that the components of the closed-vent system are unsafe to
monitor because monitoring personnel would be exposed to an immediate danger as
a consequence of complying with subsection (l)(1)(B)(ii); and
2) The
remanufacturer or other person that stores or treats the hazardous secondary
material in a hazardous secondary material management unit using a closed-vent
system adheres to a written plan that requires monitoring the closed-vent
system components using the procedure specified in subsection (l)(1)(B)(ii) as
frequently as practicable during safe-to-monitor times.