35 Ill. Adm. Code 742.717
J&E Soil Gas Equations for the Indoor Inhalation Exposure Route
Section 742.717 J&E Soil Gas Equations for the
Indoor Inhalation Exposure Route
a) This
Section sets forth the equations and parameters to be used to develop Tier 2
soil gas remediation objectives for the indoor inhalation exposure route using
the modified J&E model.
b) Equations
J&E1 and J&E2 calculate, for carcinogens and noncarcinogens,
respectively, an acceptable concentration of the contaminant of concern in
indoor air that adequately protects humans who inhale this air. Equation
J&E3 converts indoor air concentrations from parts per million volume to
milligrams per cubic meter.
c) Equation
J&E4 calculates an acceptable concentration of the contaminant of concern
in the soil gas at the source of contamination. This calculation is made using:
1) an
attenuation factor developed in accordance with Equations J&E7 through 18;
and
2) the
acceptable concentration of the contaminant of concern in indoor air calculated
in accordance with Equation J&E1 (for carcinogens) or J&E2 (for
noncarcinogens).
d) The
attenuation factor (Equation J&E7 or J&E8) accounts for the following
processes:
1) Migration
of contaminants from the source upwards through the vadose zone;
2) Migration
of contaminants through the earthen filled cracks in the building's full
concrete slab-on-grade or full concrete basement floor and walls; and
3) Mixing
of the contaminants with air inside the building.
e) Equation
J&E7 must be used when the mode of contaminant transport is both diffusion
and advection. In this scenario, the Q
soil
value equals 83.33 cm
3
/sec
as described in Section 742.505.
f) Equation
J&E8 may be used only when the mode of contaminant transport is diffusion
only. In this scenario, the Q
soil
value equals 0.0 cm
3
/sec
as described in Section 742.505. As an alternative to using Equation J&E8
pursuant to this subsection, it is permissible to use Equation J&E7, in
which case the Q
soil
value equals 83.33 cm
3
/sec as
described in Section 742.505.
g) Equations
J&E9a through J&E18 calculate input parameters for either Equation
J&E7 or J&E8 (the equations used to calculate an attenuation factor).
These equations assume there are "n" different soil layers between
the source of the contamination and the floor of the building. Equations
J&E11, 16, 17 and 18 shall be used to calculate the needed parameters for
each of the n layers (the general soil layer is referred to as soil layer "i"
and i = 1,2,…n). Equations J&E16, 17, and 18 shall also be used to calculate
needed parameters for the soil in the cracks of the building's full concrete
slab-on-grade or full concrete basement floor and walls (it is through these
cracks that contaminated soil gas is assumed to flow from the subsurface into
the building). As reflected in Equation J&E14, the only crack assumed to
be present is the floor-wall seam gap. To calculate the surface area of the
enclosed space at or below grade, Equation J&E12a shall be used for a
building with a full concrete slab-on-grade and Equation J&E12b shall be
used for a building with a full concrete basement floor and walls.
h) The
default representative subsurface temperature for Henry's Law Constant is 13
°
C. This value shall be used, as
appropriate, in all calculations needed to represent the system by which
contaminants migrate through the subsurface.
i) The
calculated soil gas remediation objective shall be compared with the soil vapor
saturation limit (C
v
sat
, Equation J&E5) for each
volatile chemical. The calculated C
v
sat
shall use the default
representative subsurface temperature specified in subsection (h). If the
calculated soil gas remediation objective is greater than C
v
sat
,
then C
v
sat
is used as the soil gas remediation objective.
j) The
calculated soil gas remediation objective shall be compared to concentrations
of soil gas collected at a depth at least 3 feet below ground surface and above
the saturated zone. If a valid sample cannot be collected, a soil gas sampling
plan shall be approved by the Agency under Tier 3.